Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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The Carbazole Synthesis From 1,4-Dichloro-1,4-dimethoxybutane

1,4-디클로로-1,4-디메톡시부탄올 이용한 카르바졸의 합성

  • Published : 1992.08.20
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Abstract

N-Substituted pyrroles were synthesized from 1,4-dichloro-1,4-dimethoxybutane and primary amines or amide in the presence of Amberlyst A-21 resin. Further reation of these N-substituted pyrroles with 1,4-dichloro-1,4-dimethoxybutane gave N-substituted carbazoles in moderate yields.

1,4-Dichloro-1,4-dimethoxybutane과 일차 아민 또는 아미드를 약 염기성인 Amberlyst A-21 resin 존재하에서 반응시켜 N-치환된 피롤을 합성하였으며, 이 피롤 화합물에 1,4-dichloro-1,4-dimethoxybutane를 다시 반응시켜 N-치환된 카르바졸을 합성하였다.

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References

  1. Chem. Rev. v.40 N. Campbell;B. M. Barclay
  2. Ann v.16 H. Graeke;F. Utlman
  3. Can. J. Chem. v.43 A. H. Kelly;D. H. Mcleod
  4. J. Heterocyclic Chem. v.18 M. Kuroki;V. Tsunashiba
  5. Tetrahedron Lett. v.27 C. Kashima;S. Hibi;T. Maruyama;Y. Omote
  6. Acta Chem. Scand v.9 P. Nedenskov;N. Elming;J. T. Nielsen;N. Clauson-Kaas
  7. Tetrahedron Lett. T. H. Chan;S. D. Lee
  8. Tetrahedron Lett. S. D. Lee;M. A. Brook;T. H. Chan
  9. J. Org. Chem. v.48 T. H. Chan;S. D. Lee
  10. Catalogue of Handbook of Fine Chemicals Aldrich Chem. Co.
  11. J. Chem. Soc. H. A. Potts;G. F. Smith
  12. Adv. Heterocylic Chem. v.2 G. F. Smith