Bulletin of the Korean Chemical Society

  • 제13권6호
  • /
  • Pages.636-642
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  • 1992
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Preferential Solvation and Statistical Analysis for Solvent Polarity Parameters in MeOH Binary Mixtures

  • 발행 : 1992.12.20
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초록

Preferential solvation (PS) phenomena of solutes based on solvent polarity, $E_T$ and AN, were studied by UV/vis. and NMR spectra in MeOH binary mixtures. According to the extent of solvent-solvent interaction, different solvation phenomena were found. PS concept was applied to explain the reactivity of tert-butyl halides solvolysis. The findings of solvation phenomena have been related to the rate of solvolysis and PS suggested as a reason for the solvent dependence of the rates of reaction. Moreover, we found that the results of principal components analysis using six parameters are in good accordance with the results of PS phenomena in mixed methanol systems.

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참고문헌

  1. Angew. Chem. Int. Ed. Engl. v.18 C. Reichardt
  2. Solvents and Solvent Effects in Organic Chemistry C. Reichardt
  3. J. Chem. Soc., Faraday Trans. I v.78 Y. Kondo;S. Kusabayashi
  4. J. Chem. Soc., Faraday Trans. I v.84 no.3 J. G. Dawber;J. Ward;R. A. Williams
  5. Bull. Korean Chem. Soc. v.4 I. Lee;B. S. Lee;I. S. Koo;S. C. Sohn
  6. Bull. Korean Chem. Soc. v.11 Y. Sakong;S. C. Kim;I. Lee
  7. Liebigs Ann. Chem. v.661 K. Dimroth;C. Reichardt;T. Siepmann;F. Bohlmann
  8. Liebigs Ann. Chem. v.752 C. Reichardt
  9. Monatsch Chem. v.106 U. Mayer;V. Gutmann;W. Gerger
  10. Monatsch Chem. v.108 U. Mayer;V. Gutmann;W. Gerger
  11. Pure Appl. Chem. v.51 U. Mayer
  12. Water, A Comprehensive Treatise v.6 J. B. F. N. Engberts;F. Franks(ed.)
  13. Acc. Chem. Res. v.10 C. H. Langford;J. P. K. Tong
  14. Pure Appl. Chem. v.49
  15. J. Am. Chem. Soc. v.94 V. S. Sastri;R. W. Henwood;S. Behrendt;C. H. Langford
  16. J. Phys. Chem. v.87 K. Remerle;J. B. F. N. Engberts
  17. Spectrochim. Acta v.44A N. B. Toselli;J. J. Silber;J. D. Anunzita
  18. J. Am. Chem. Soc. v.98 M. J. Kamlet;R. W. Taft
  19. J. Am. Chem. Soc. v.99 M. J. Kamlet;J. L. M. Abboud;R. W. Taft
  20. Prog. Phys. Org. Chem. v.13 J. L. M. Abboud;M. J. Kamlet;R. W. Taft
  21. J. Solution Chem. v.14 R. W. Taft;J. L. M. Abbound;M. J. Kamlet;M. H. Abraham
  22. Inorg. Nucl. Chem. Letters v.2 V. Gutmann;E. Wychera
  23. Coord Chem. Rev. v.2 V. Gutmann
  24. Coord Chem. Rev. v.18 V. Gutmann
  25. Factor Analysis in Chemistry E. R. Malinowsky;D. G. Howery
  26. Chemometrics M. A. Saraf;D. L. Illman;B. R. Kowalski
  27. Bull. Chem. Soc. Jpn. v.45 Y. Fukuda;K. Sone
  28. Anal. Chem. v.42 D. H. Live;S. I. Chan
  29. J. Am. Chem. Soc. v.91 E. M. Arnett;L. Joris;E. Mitchell;T. S. S. R. Murty;T. M. Gorrie;P. v. R. Schleyer
  30. Organic Reactivity(Tartu) v.20 I. A. Koppel;J. B. Koppel
  31. J. Am. Chem. Soc. v.108 T. Mitsuhashi
  32. J. Chem. Soc., Perkin Trans. II M. H. Abraham;R. J. Abraham
  33. J. Chem. Soc., Perkin Trans. II M. H. Abraham;R. M. Doherty;M. J. Kamlet;J. M. Harris;R. W. Taft
  34. J. Korean Chem. Soc. v.30 Y. Sakong;S. C. Kim;J. B. Choo

피인용 문헌

  1. Online Size Exclusion Chromatography-Fourier Transform Infrared Spectroscopy (FTIR): Investigation of Preferential Solvation Effects vol.3, pp.4, 1992, https://doi.org/10.1080/10236669708032773