Bulletin of the Korean Chemical Society

  • 제13권6호
  • /
  • Pages.627-631
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  • 1992
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Iridium(Ⅲ) Insertion into an Aromatic C-H Bond and Si-H Bond

  • Yang Nam Keun (Department of Chemistry Education, Korea National University of Education) ;
  • Chung Dae-Eun (Department of Chemistry Education, Korea National University of Education) ;
  • Ko Jaejung (Department of Chemistry Education, Korea National University of Education) ;
  • Kang Sang Ook (Department of Chemistry, College of Natural Sciences, Korea University)
  • 발행 : 1992.12.20
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초록

The dihydrido iridium(Ⅲ) complex [$Ir(PPh_3)_2H_2(ac)_2$]$BF_4$ (ac=acetone) reacts with 2-phenylpyridine and 7,8-benzoquinoline to yield the C-H activated complexes [$Ir(PPh_3)_2$H(ac)(L)]$BF_4$ (L= phenylpyridine; 7,8-benzoquioline). The dihydrido iridium(Ⅲ) complex [$Ir(PPh_3)_2H_2(ac)_2$]$BF_4$ also reacts with triaklysilane via an oxidative addition reaction to yield the trihydrido iridium complexes [$Ir(PPh_3)_2H_3SiR_3$]$BF_4$ (R =Et and Ph). The structual configuration was studied by conventional spectroscopy.

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참고문헌

  1. J. Am. Chem. Soc. v.105 P. L. Watson
  2. J. Am. Chem. Soc. v.104 J. K. Hoyano;W. A. G. Graham
  3. J. Am. Chem. Soc. v.104 A. H. Janowicz;R. G. Bergman
  4. J. Am. Chem. Soc. v.106 M. J. Max;J. M. Stryker;J. M. Buchanan;C. A. Kovac;R. G. Bergman
  5. Coord. Chem. Rev. v.24 A. G. Shilov;A. A. Shteinman
  6. J. Chem. Soc. Chem. Commun. D. Baudry;M. Ephritikhine;H. Felkin
  7. J. Am. Chem. Soc. v.104 R. H. Crabtree;P. C. Demou;D. Eden;J. M. Mihelcic;C. A. Parnell;J. M. Quirk;G. E. Morris
  8. Pure Apple. Chem. v.50 A. E. Shilov
  9. J. Chem. Soc. Chem. Commun. G. B.Shul'pin;G. V. Nizova;A. E. Shilov
  10. J. Am. Chem. Soc. v.105 J. T. Groves;T. E. Nemo
  11. J. Am. Chem. Soc. v.105 J. A. Smegal;B. C. Schardy;C. L. Hall
  12. Organometallics v.3 R. A. Periana;R. G. Bergman
  13. J. Chem. Soc. Chem. Commun. M. Gomez;D. J. Robinson;P. M. Maitlis
  14. J. Am. Chem. Soc. v.101 C. A. Tolman;S. D. Ittel;A. D. English;J. P. Jesson
  15. J. Am. Chem. Soc. v.106 S. Sprose;K. A. King;P. J. Spellance;R. J. Watte
  16. J. Organomet. Chem. v.246 J. Selbin;M. A. Gutierrez
  17. Inog. Chem. v.26 A. Albinati;C. G. Anklin;F. Ganazzoli;H. Ruegg;P. S. Pregosin
  18. J. Organomet. Chem. v.284 J. Ko;W. C. Hee;P. G. Williard;W. M. Risen
  19. Bull. Kor. Chem. Soc. v.7 J. Ko;W. C. Joo;Y. K. Kong
  20. Bull. Kor. Chem. Soc. v.8 J. Ko;W. C. Joo
  21. Purification of Laboratory Chemicals D. D. Perrin;W. L. F. Armarego
  22. Inorg. Chem. v.24 R. H. Crabtree;E. M. Holt;M. Labin;S. M. Morehouse
  23. J. Organomet. Chem. v.243 C. G. Ankin;P. S. Pregosin
  24. Organometallics v.8 M. Lavin;E. M. Holt;R. H. Crabtree
  25. Inorg. Chem. v.28 F. Neve;M. Ghedini;A. Tiricchio;F. Ugozzoli
  26. J. Chem. Soc. Chem. Commun. M. Green;J. A. K. Howard;J. Proud;J. L. Spencer;F. G. A. Stone
  27. J. Chem. Soc. Dalton Trans. M. Ciriano;M. Green;J. A. K. Howard;J. Proud;J. L. Spencer;F. G. A. Stone;C. A. Tsipis
  28. J. Organomet. Chem. v.118 R. Ros
  29. Inorg. Chem. v.22 R. H. Crabtree;R. J. Vriate
  30. Organometallics v.5 R. H. Crabtree;J. W. Faller;M. F. Mellea;J. M. Quirk
  31. J. Am. Chem. Soc. v.101 no.14 J. F. Harrod;G. Hamer;W. Yorke
  32. J. Chem. Soc.(A) F. Glocking;M. D. Wilbey
  33. Transition Metal Hydrides J. P. Jesson;E. L. Muetterties(ed.)
  34. Inorg. Chem. v.26 J. Wu;M. K. Reinking;P. E. Fanwick;C. P. Kubiak