Bulletin of the Korean Chemical Society

  • 제13권6호
  • /
  • Pages.595-599
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  • 1992
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Temperature Dependence of Carbon-13 Shieldings as a Probe for Conformational Equilibra

  • Jung Miewon (Department of Chemistry, Sungshin Women's University)
  • 발행 : 1992.12.20
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초록

The temperature dependence of C-13 chemical shifts are observed for the cyclooctanone arylhydrazones. The temperature-dependent chemical shifts for these derivatives are explained by postualating the existence of two equilibrating structures. In addition, the assignment between the $^{13}C$ signals of methylene carbon pairs can be done by application of the ${gamma}$ -substituent effect.

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참고문헌

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