Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Chemistry of Ruthenium Hydridonitrosyl Complexes Containing Chelating Triphosphines I-Structures of RuH(NO)$P_3$ ($P_3$ : Chelating Triphosphines)

  • Ik Mo Lee (Department of Chemistry, Inha Universtiy) ;
  • Devon W. Mee (Department of Chemistry, The Ohio State University) ;
  • Judith Gallucci (Department of Chemistry, The Ohio State University)
  • Published : 1992.10.20
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Abstract

Chelating triphosphines were applied to freeze the fluxionality and to minimize the number of isomers found in the monophosphine analogues and this technique was proved to be useful. RuH(NO)$P_3$($P_3$; Cyttp, ttp and etp) complexes were characterized to have similar trigonal bipyramidal structures with linear NO groups. Cyttp prefers to have a meridional geometry while etp prefers a facial one and ttp complexes are mixture of these two isomers. The crystal structure of RuH(NO)(Cyttp) has been determined to have a distorted trigonal bipyramidal structure with a linear NO in the equatorial plane. The crystals are orthorhombic, space group $P_{nma}$, with unit cell dimensions a = 16.356(2), b = 20.474(2), c = 10.915(l) ${\AA}$, V = 3655 ${\AA}^3$, Z = 4, R = 0.035 and $R_w$ = 0.034 for the 2900 intensities with $F_o^2 >3{\sigma}(F_o^2)$ and the 208 variables.

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References

  1. Chem. Rev. v.72 H. D. Kaesz;R. B. Salliant
  2. Homogeneous Transition-Metal Catalysis C. Masters
  3. J. Am. Chem. Soc. v.93 S. T. Wilson;J. A. Osborn
  4. J. Chem. Soc. (A) C. A. Reed;W. R. Roper
  5. J. Organomet. Chem. v.42 R. P. Stewart Jr.;N. Okamoto;W. A. G. Granam
  6. Inorg. Chem. v.18 P. Legzidins;D. T. Martin
  7. Organometallics v.6 P. Legzidins;D. T. Martin;F. W. B. Einstein;R. H. Jones
  8. J. Chem. Soc. Dalton R. A. Sanchez-Delgado;G. Wilkinson
  9. Inorg. Chem. v.15 D. L. Dubois;D. W. Meek
  10. Acc. Chem. Res. v.14 D. W. Meek;T. J. Mazanec
  11. Inorg. Chem. v.11 C. G. Pierpont;R. Eisenberg
  12. Inorg. Chem. v.10 D. M. P. Mingos;J. A. Ibers
  13. Inorg. Chem. v.13 G. R. Clark;J. M. Waters;K. R. Whittle
  14. Ph. D. Dissertation, The Ohio State Univeristy D. L. Dubois
  15. Inorg. Synth. v.17 J. S. Bradley;G. Wilkinson
  16. Ph. D. Dissertation, The Ohio State Univeristy L. M. Green
  17. Ph. D. Dissertation, Harvard University S. T. Wilson
  18. Programs used for data reduction are from the CRYM crystalographic computing package D. J. Duchamp;B. L. Trus;B. J. Westphal
  19. DIRDIF; Direct Methods for Difference Structures P. T. Beurskens;W. P. Bosman;H. M. Doesburg;R. O. Gould;Th. E. M. Van den Mark;P. A. J. Prick;J. H. Noordik;G. Beurskens;V. Parthasarathi;H. J. Bruins Slot;R. C. Haltiwanger
  20. SHELX-76. Program for crystal Structure Determination G. M. Sheldrick
  21. J. Chem. Soc. J. J. Daly
  22. J. Am. Chem. Soc. v.95 T. E. Nappier Jr.;D. W. Meek;R. M. Kirchner;J. A. Ibers
  23. Chem. Commun. A. C. Skapski;P. G. H. Troughton
  24. Inorg. Chem. v.9 K. W. Muir;J. A. Ibers
  25. Transition Met. Chem. v.12 D. M. P. Mingos;D. J. Sherman;I. D. Williams
  26. Inorg. Chem. v.13 R. Hoffmann;M. M. L. Chen;M. Elian;A. R. Rossi;D. M. P. Mingos
  27. Chem. Commun. G. R. Clark;K. R. Grundy;W. R. Roper;J. M. Waters;K. R. Whittle
  28. Inorg. Chem. v.8 D. J. Hodgson;J. A. Ibers
  29. Chem. Commun. P. B. Hitchcock;M. McPartlin;R. Mason
  30. Cryst. Struct. Commun. v.3 D. Hall;R. B. Williamson
  31. Inorg. Chem. v.13 A. P. Gaughan Jr.;B. J. Corden;R. Eisenberg;J. A. Ibers
  32. J. Chem. Soc.(A) R. Mason;A. D. C. Towl
  33. Bull. Korean Chem. Soc. I. M. Lee;Y. J. Kim;O. J. Cho;D. W. Meek
  34. Chem. Rev. v.81 P. E. Garrou
  35. Prog. Inorg. Chem. v.32 R. R. Holmes
  36. Coord. Chem. Rev. B. F. Hoskins;F. D. Williams
  37. Organometallics v.7 P. Legzidins;B. Wassink;F. W. B. Einstein;R. H. Jones
  38. Inorg. Chem. v.25 W. H. Hohman;D. J. Kountz;D. W. Meek
  39. J. Am. Chem. Soc. v.110 C. Bianchini;D. Masi;A. Meli;M. Peruzzini;F. Zanobini
  40. Inorg. Synth. v.13 R. A. Schunn;E. R. Wonchoba
  41. J. Chem. Soc. (A) F. D. Charentenary;J. A. Osborn;G. Wilkinson
  42. Multinuclear NMR C. J. Jameson;J. Mason(ed.)
  43. J. Am. Chem. Soc. v.98 A. D. English;P. Meakin;J. P. Jesson
  44. J. Am. Chem. Soc. v.91 J. A. McGinnety;N. C. Payne;J. A. Ibers
  45. J. Chem. Soc. (A) M. C. Hall;B. T. Kilbourn;K. A. Taylor
  46. J. Am. Chem. Soc. v.94 P. Meakin;E. L. Muetterties;J. P. Jesson
  47. Bull. Korean Chem. Soc. I. M. Lee;D. W. Meek;J. Gallucci
  48. J. Chem. Soc. (A) J. M. Jenkins;B. L. Shaw
  49. Inorg. Chem. v.11 M. Aktar;P. D. Ellis;A. G. MacDiarmid;J. D. Odom

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