Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Syntheses and Phase-transfer Catalytic Activities of Monoazacrown Ethers

  • Shim Jae Hu (Department of Chemical Engineering, Dongguk University) ;
  • Chung Kwang Bo (Department of Chemical Engineering, Dongguk University) ;
  • Masao Tomoi (Department of Applied Chemistry, Faculty of Engineering, Yokohama National University)
  • Published : 1992.06.20
Download PDF
⟨ Previous Next ⟩

Abstract

Preparative methods for and catalytic activities of monoaza-18-crown-6 or monoaza-15-crown-5 in the reaction of 1-bromooctane with aqueous KI or NaI were investigated. Monoazacrown ethers were prepared by debenzylation of N-benzylmonoazacrown ethers, obtained from the reaction of N-benzyldiethanolamine and oligoethylene glycol ditosylate. The phase-transfer catalytic activity of N-benzylmonoazacrown ethers was higher than that of the corresponding monoazacrown ethers.

Keywords

References

  1. J. Am. Chem. Soc. v.89 C. J. Pedersen
  2. Chem. Rev. v.74 J. J. Christensen;D. J. Eatough;R. M. Izatt
  3. Tetrahedron v.29 B. Dietrich;J. M. Lehn;J. P. Sauvage;J. Blanzan
  4. Chem. Rev. v.11 J. M. Lehn
  5. J. Am. Chem. Soc. v.107 R. A. Schultz;B. D. White;D. M. Dishong;K. A. Arnold;G. W. Gokel
  6. Chem. Ber. v.118 H. G. Lohr;F. Vogtle
  7. Tetrahedron Lett. v.28 B. D. White;K. A. Arnold;G. W. Gokel
  8. Chem. Soc. Rev. v.15 I. O. Sutherland
  9. J. Org. Chem. v.52 M. W. Hosseini;J. M. Lehn;S. R. Duff;K. Gu;M. P. Mertes
  10. Science v.227 J. M. Lehn
  11. J. Am. Chem. Soc. v.107 P. G. Yohannes;M. P. Mertes;K. B. Mertes
  12. Tetrahedron Lett. v.21 J. M. Lehn;P. Vierling
  13. Chem. Rev. v.85 R. M. Izatt;J. S. Bradshaw;S. A. Nielsen;J. D. Lamb;J. J. Christensen;D. Sen
  14. Coordination Chemistry of Macrocyclic Compound J. D. Lamb;R. M. Izatt;J. J. Christensen;D. K. Eatough;G. A. Melson(ed.)
  15. J. Chem. Soc. Pak. v.5 A. R. Kauser
  16. Kontakte (Merck) E. Weber
  17. Kontakte (Merck) E. Weber
  18. Acta Chem. Scand. v.26 J. Dale;P. O. Kristiansen
  19. Tetrahedron Lett. v.4 G. W. Gokel;B. J. Garcia
  20. J. Chem. Soc. Commun. M. J. Calverley;J. Date
  21. Tetrahedron Lett. v.22 H. Maeda;Y. Nakatsuji;M. Okahara
  22. Tetrahedron Lett. R. N. Greene
  23. J. Am. Chem. Soc. v.93 H. K. Frensdorff
  24. J. Org. Chem. v.53 J. S. Bradshaw;K. E. Krakowiak
  25. J. Chem. Soc., Perkin Trans. v.1 M. R. Johnson;I. O. Sutherland;R. F. Newton
  26. J. Chem. Soc., Perkin Trans. v.1 M. R. Johnson;N. F. Jones;I. O. Sutherland
  27. Angew. Chem. Int. Ed. Engl. v.11 C. J. Pederson;H. K. Frensdorff

Cited by

  1. ChemInform Abstract: Syntheses and Phase-Transfer Catalytic Activities of Monoazacrown Ethers. vol.23, pp.46, 1992, https://doi.org/10.1002/chin.199246198
  2. Steric and Stereoelectronic Effects in Aza Crown Ether Complexes[1] vol.1998, pp.7, 1992, https://doi.org/10.1002/(sici)1099-0690(199807)1998:7<1379::aid-ejoc1379>3.0.co;2-9