Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

N-Alkylatin of Secondary Amines in Nickel(II) Complexes of Polyaza Macrotricyclic Ligands

  • Suh, Paik-Myunghyun (Department of Chemistry Education, Seoul National University) ;
  • Kim, Myung-Jin (Department of Chemistry Education, Seoul National University) ;
  • Kim, Hyun-Kyung (Department of Chemistry Education, Seoul National University) ;
  • Oh, Kye-Young (Department of Chemistry Education, Seoul National University)
  • Published : 1992.02.20
Download PDF
⟨ Previous Next ⟩

Abstract

The secondary nitrogen donors of the Ni(II) complexes of macrotricyclic ligands 8-methyl-1,3,6,8,10,13,15-heptaazatricyclo $[13.1.1.1^{13,15}]$octadecane (A) and 1,3,6,9,11,14-hexaazatricyclo $[12.2.1.1^{6,9}]$octadecane (B) are N-alkylated and the Ni(II) complexes of $N-Me_2A,\;N-Et_2A,\;and\;N-Me_2B$ are obtained. The Ni(II) complexes of $N-Me_2A\;and\;N-Et_2A$ are stable in acidic aqueous solutions while that of $N-Me_2B$ decomposes relatively rapidly. The N-alkylation leads to the decrease in the ligand field strength as well as an anodic shift in both of the oxidation and the reduction potentials of the Ni(II) complexes.

Keywords

References

  1. J. Am. Chem. Soc. v.96 F. V. Lovecchio;E. S. Gore;D. H. Busch
  2. Isr. J. Chem. v.25 N. Jubran;H. Cohen;D. Meyerstein
  3. Inorg. Chem. v.18 L. Sabatini;L. Fabbrizzi
  4. Inorg. Chem. v.25 E. K. Barefield;G. M. Freeman;D. G. Van Derveer
  5. Inorg. Chem. v.25 M. Ciampolini;L. Fabbrizzi;A. Perotti;F. Pezzini;A. Poggi
  6. Inorg. Chem. v.12 E. K. Barefield;F. Wagner
  7. Inorg. Chem. v.15 F. Wagner;E. K. Barefield
  8. Inorg. Chem. v.24 N. Jubran;G. Ginzburg;H. Cohen;Y. Koresh
  9. Inorg. Chem. v.26 M. P. Suh;W. Shin;H. Kim;C. H. Koo
  10. Inorg. Chem. v.28 M. P. Suh;W. Shin;S.-G. Kang;M. S. Lah;T. M. Chung
  11. Inorg. Chem. v.30 M. P. Suh;S. G. Kang;V. L. Goedken;S. H. Park
  12. Inorg. Chem. v.27 M. P. Suh;S.-G. Kang
  13. Purification of Laboratory Chemicals D. D. Perrin;W. L. F. Armarego;D. R. Perrin
  14. J. Chem. Soc. Dalton Trans. K. Miyamura;M. Kohzuki;R. Narushima;M. Saburi;Y. Gohshi;S. Tsuboyama;K. Tsuboyama;T. Sakurai

Cited by

  1. Biotinylation of aminopyridine-based macrocycles and metallomacrocycles and inclusion of biotinylated iron(II) complex in avidin vol.64, pp.1, 2009, https://doi.org/10.1007/s10847-009-9531-z