Bulletin of the Korean Chemical Society

  • 제13권1호
  • /
  • Pages.45-48
  • /
  • 1992
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Carbonylation of Bromo(Bromomethyl)Benzenes to Alkyl Carboalkoxyphenylacetates Catalyzed by Cobalt Carbonyl

  • Shim, Sang-Chul (Department of Industrial Chemistry, Kyungpook National University) ;
  • Doh, Chil-Hoon (Department of Industrial Chemistry, Kyungpook National University) ;
  • Lee, Dong-Yub (Department of Industrial Chemistry, Kyungpook National University) ;
  • Youn, Young-Zoo (Department of Industrial Chemistry, Kyungpook National University) ;
  • Lee, Seung-Yub (Department of Industrial Chemistry, Kyungpook National University) ;
  • Chae, Shin-Ae (Department of Industrial Chemistry, Kyungpook National University) ;
  • Oh, Dae-Hee (Department of Surface Coating Engineering, Pusan National Univerwity of Technology) ;
  • Oh, Hun-Seung (Lucky R & D Center, Science Town)
  • 발행 : 1992.02.20
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초록

A synthetic method for bis-carbonylation of bromo(bromomethyl)benzenes was described. Alkyl carboalkoxyphenylacetates were easily prepared by the carbonylation of benzylic and arylic bromide moieties in bromo(bromomethyl)benzenes with alcohols in the presence of $K_2CO_3,\;CH_3I$, and a catalytic amount of cobalt carbonyl under the atmospheric pressure of carbon monoxide at room temperature in good to excellent yields. The base played a decisive role in the selectivity of product and $K_2CO_3$ was the best one among bases used.

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참고문헌

  1. J. Am. Chem. Soc. v.85 R. F. Heck;D. S. Breslow
  2. J. Organomet. Chem. v.285 F. Francalanci;E. Bincini;A. Gardano;M. Vincenti;M. Foa
  3. J. Organomet. Chem. v.285 M. Foa;F. Francalanci;E. Bencini;A. Gardano
  4. J. Korean Chem. Soc. v.34 S. C. Shim;C. H. Doh;Y. Z. Yoon;C. S. Cho;B. W. Woo
  5. J. Korean Chem. Soc. v.35 S. C. Shim;C. H. Doh;Y. Z. Yoon;C. S. Cho;B. W. Woo;D. H. Oh
  6. Adv. Organomet. Chem. v.2 R. B. King
  7. J. Org. Chem. v.52 M. Miura;F. Akase;M. Nomura
  8. J. Organomet. Chem. v.243 T. Funabiki;H. Nakamura;S. Yoshida

피인용 문헌

  1. ChemInform Abstract: Carbonylation of Bromo(bromomethyl)benzenes to Alkyl Carboalkoxyphenylacetates Catalyzed by Cobalt Carbonyl. vol.23, pp.22, 1992, https://doi.org/10.1002/chin.199222131