Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Preparation and Analysis of Activated Carbon Fiber from PAN Precursor(I)

PAN 선구체로부터 활성 탄소섬유의 생산과 분석(I)

  • 김진홍 (전북대학교 공과대학 섬유공학과) ;
  • 이화선 (전북대학교 공과대학 섬유공학과) ;
  • 박병기 (전북대학교 공과대학 섬유공학과) ;
  • 정경락 (전북대학교 공과대학 화학공학과) ;
  • 김공주 (전북대학교 공과대학 섬유공학과)
  • Published : 1992.12.01
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Abstract

In the PAN-based ACF manufacturing system stabilization step was improved with chemical treatment (preoxidation) in order to yield higher carbon content and to avoid excessive fragmentation during carbonization and activation process. The optimal condition of preoxidation was at 18$0^{\circ}C$ for 4 minutes in sodium glyceroxide in glycerine (concentration of NaOH was 0.02 meq/g). To investigate low temperature stabilization effect, preoxidized PAN fiber heated 22$0^{\circ}C$ to 26$0^{\circ}C$ as a function of treatment time and oxidative gas atmosphere, and analysed by infrared spectrum and TGA. As a results of IR and TGA, it was clear that impregnated[preoxidative] PAN had 14% higher residual than untreated PAN at 100$0^{\circ}C$ and the optimal condition of stabilization was at 26$0^{\circ}C$ for 3.5 hours within $N_2$ atmosphere.

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