CaO를 첨가한 2.5Y-TZP 세라믹스의 저온열화 거동

Low Temperature Degradation Behavior for CaO Doped 2.5Y-TZP Ceramics

  • 발행 : 1992.05.01

초록

The effects of CaO addition on the low temperature degradation behavior of 2.5Y-TZP ceramics were investigated. Y2O3-CaO-ZrO2 ceramics were prepared from the commercial Y-TZP powder added within 1 mol% of CaO. Fully tetragonal phase could be obtained at each composition under sintering condition of 1500$^{\circ}C$ for 1 hour. As the amount of CaO increased, grain size was decreased. From the result of heat treatment at 200$^{\circ}C$, volume fraction of monoclinic phase formed on the surface of each specimen was decreased with higher CaO amount. Stability of tetragonal ZrO2 phase for low temperature heat treatment was increased by CaO addition without the degradation of mechanical properties.

키워드

참고문헌

  1. Nature v.258 Ceramic Steel? R.C. Garvie;R.H. Hannink;R.T. Pascoe
  2. J. Am. Ceram. Soc v.69 no.8 Mechanical Properties of Toughened ZrO₂-Y₂O₃Ceramics T. Masaki
  3. J. Mater. Sci v.20 Transformation of Yttria Partially Stabilized Zirconia by Low Temperature Annealing in Air T. Sato;S. Ohtaki;M. Shimada
  4. Am.Ceram.Soc.Bull v.64 Transformation of Ceria-Doped Tetragonal Zirconia Polycrystals by Annealing in Water T.Sato;M.Shimada
  5. J. Am. Ceram. Sco. v.69 Significance of Internal Stresses for the Martensitic Transformation in Yttria-Stabilized Tetragonal Zirconia Polycrystals During Degradation S. Schmauder;H. Schubert
  6. Science of Ceramics v.14 T. Sato;T. Fukushima;T. Endo;M. Shimada
  7. Solid State Ionics v.3;4 Phase Change and Mechanical Properties of ZrO₂-Y₂O₃Solid Electrolyte After Aging K. Kobayashi;H. Kuwajima;T. Masaki
  8. J. Am. Ceram. Soc. v.66 no.3 Role of Water Vapor in Crystallite Growth and Tetragonal-Monoclinic Phase Transformation of ZrO₂ Y. Murase;E. Kato
  9. J. Mater. Sci. v.5 Improvement of Thermal Stability of Yttria-Doped Tetragonal Zirconia Polycrystals by Doping CeO₂on the Surface T. Sato;S. Ohtaki;T. Endo;M. Shimada
  10. Advances in Ceramics v.24 Improvement to the Thermal Stability of Yttria-Doped Tetragonal Zirconia Polycrystals by Alloying with Various Oxides T. Sato;S. Ohtaki;T. Endo;M. Shimada;S. Somiya(ed.);N. Yamamoto(ed.);H. Hanagida(ed.)
  11. J. Am. Ceram. Soc. v.72 no.2 Prevention of Low-Temperature Surface Transformation by Surface Recrystallization in Yttria-Doped Tetragonnal Zirconia P.J. Whalen;F. Reidinger;R.F. Antrim
  12. J. Am. Ceram. Soc. v.73 no.9 Development of Superplastic Structural Ceramics I.W. Chen;L.A. Xue
  13. J. Am. Ceram. Soc. v.67 no.6 Phase Analysis in Zirconia System R.C. Garvie;P.S. Nicholson
  14. J. Am. Ceram. Soc. v.67 no.6 Calibration Curve for Quantitive Analysis of the Monoclinic Tetragonal ZrO₂System by X-ray Diffraction H. Toraya;M. Yoshimura;S. Somiya
  15. J. Am. Ceram. Soc. v.68 no.12 Transformation of Yttria-Doped Tetragonal ZrO₂Polycrystals by Annealing under Controlled Humidity Conditions T. Sato;S. Ohtaki;T. Endo;M. Shimada
  16. Cer Sci Eng. Proc. Lee;Brun
  17. 第21回 窯業基礎討論會講演旨集 新原皓一
  18. Advances in Ceramics v.24 The Aging Behavior of Ultrafine-grained Y-TZP in Hot Water A.J.A. Winnubst;A.J. Burggraaf;S. Somiya(ed.);N. Yamamoto(ed.);H. Hanagida(ed.)