The Crystallization Kinetics of CaO-MgO-Al2O3-SiO2 Glass System Using Thermal Analysis

열분석을 이용한 CaO-MgO-Al$_2$O$_3$-SiO$_2$의 결정화 기구의 연구

  • 김형순 (순천대학교 금속공학과 무기재료분야)
  • Published : 1992.01.01

Abstract

Some of non-isothermal analysis methods are applied to CaO-MgO-Al2O3-SiO2 glass system to find the kinetics parameters of crystallisation, activation energy, Avrami component and frequency factor. The results using the non-isothermal analysis were compared to that of microstructure experiment. Analysis of the result has enabled to some methods to be to recommend as being the most appropriate equation to use in a glass system. It was shown that in the thermal analysis using the non-isothermal method of Kissinger, Augis-Bennett, Bansal, and Marotta, the calculation of activation energy is not much different, while Avrami component and frequency factor are different from applied each methods.

Keywords

References

  1. Glass-Ceramics, (2nd ed.) P.W. McMillan
  2. Glass-Ceramic Materials Z. Stranad
  3. Energy Conservation in Industry Applications and Techniques P.S. Rogers;J. Williamson;J.F. Bell;M. Cambell;A.S. Strub(ed.);H. Ehrigner(ed.)
  4. Anal. Chem. v.29 Reaction Kinetics in Differential Thermal Analysis H.E. Kissinger
  5. Am. Ceram. Soc. Nucleation and Crystallisation of Glasses R.L. Thakur;L. Hench(ed.);S.W. Freiman(ed.)
  6. Polymer v.12 Kinetics of Non-Isothermal Crystallization T. Ozawa
  7. J. Non-Cryst. Solids v.27 A Method for Evaluating Viscosites of Metallic Glasses from the Rates of Thermal Transformation H.S. Chen
  8. J. Thermal. Anal. v.13 Calculation of the Avrami Parameter for Heterogeneous Solid-State Reactions Using a Modification of the Kissinger Method J.A. Augis;J.D. Bennett
  9. Phy Chem Glasses v.20 Kinetics Study of Crystallisation of Glasses by Differential Scanning Calorimeter K. Matusita;S. Sakka
  10. Thermochim Acta. v.25 Kinetics of Devitrification and Differential Thermal Analysis A. Marotta;A. Buri
  11. J. Am. Ceram. Soc. v.66 Kinetics of Crystallisation of ZrF₄-BaF₂-LaF₃Glass by Differential Scaning Calormetry N.P. Bansal;R.H. Doremus;C.T. Moynihan;A.J. Bruce
  12. J. Mat. Sci. v.24 Sintering and Crystallisation Phenomema in Silceram Glass H.S. Kim;R.D. Rawlings;P.S. Rogers
  13. Bull. Kor. Ceram. Soc. H.S. Kim
  14. J. Non-Cryst Solid v.27 Glasses and Glass-Ceramics from Naturally Occurring CaO-MgO-Al₂O₃-SiO₂Materials L.J. Shelestak;R.A. Chavez;J.D. Mackenzie
  15. J. Non-Cryst Solids v.41 A kinetics Treatment of Glass Formation: Ⅳ, Crystallisation on Reheating a Glass P.I.K. Onorato;D.R. Uhlimann;R.W. Hopper
  16. J. Non-Cryst. Solids v.54 Application of Thermoanalytical Techniques to the Study of Crystallisation Kinetics in Glass-Forming Liqiuds H. Yinnon;D.R. Uhlmann
  17. J. Am. Ceram. Soc. v.74 Crystallisation Kinetics of a Lithia-Silica; Effect of Sample Characteristics and Thermal Analysis Measurement Techniques C.S. Ray;W. Hung;D.E. Day
  18. Mat. Sci. Forum v.5 Effect of Composition on the Crystallisation Behaviuor of Heavy Metal Fluoride Glasses N.P. Bansal;R.H. Doremus;C.T. Moyniban;A.J. Bruce
  19. Mat. Sci. Forum v.5 Devitrification Study of ZrF₄-Based Glasses M.A. Esnault-Grosdemouge;M. Matecki;M. Polain
  20. J. Non-Cryst. Solid v.129 Surface Crustallisation Kinetics in Soda-Lime-Silica Glasses E.D. Zanotto
  21. J. Mat. Sci. v.26 The Crystallization of Diabase Glass V. Zmdarsic-Pongrac;D. Kolar
  22. Hradec, Kralove v.15 Informativni prehled statny Vyzkumny Ustav Sklarsky J. Voldan
  23. Br. Ceram. Trans. J. v.88 Quantitative Determination of Crystalline and Amorphous Phases in Glass-Ceramics by X-ray Diffraction Analysis H.S. Kim;R.D. Rawlings;P.S. Rogers