한국섬유공학회지 (Textile Science and Engineering)

한국섬유공학회 (The Korean Fiber Society)
권호 표지

음이온 개환중합에 의한 나일론 6-폴리에틸렌 글리콜 블록공중합체의 합성과 물성(I)

Synthesis of Nylon 6-Poly(Ethylene Glycol) Block Copolymer by Anionic Ring Opening Polymerization and Its Properties (I)

  • 발행 : 1992.11.01

⟨ 이전 논문 다음 논문 ⟩

초록

Nylon 6-poly(ethylene glycol) -nylon 6 type block copolyrners(PEG-b-nylon 6) were prepared by anionic copolymerization of $\varepsilon$-caprolactam and $\varepsilon$-caprolactam-blocked PEG-hexa-methylene diisocyanate prepolymer with NaH. In this anionic polymerization process, it was possible to increase the polymerization reaction rate at lower temperature than that of the condensation polymerization process employed commercially in the nylon 6 production. It was shown that the molecular weight of PEG-b-nylon 6 is higher than that of a commercial nylon 6 and is increased with increasing the PEG content in the block copolymer.

키워드

참고문헌

  1. Sen-i Gakkaishi v.25 K.Suzuki;I.Kido;N.Takenawa;K.Yamazaki
  2. J. Appl. Polym. Sci. v.19 I.M.Trivedi;P.C.Mehta;K.N.Rao;M.H.Rao
  3. Eur. Polym. J. v.17 M.B.Huglin;J.Smith
  4. J. Appl. Polym. Sci. v.28 A.K.Mukherjee;H.S.Sachdev;A.Gupata
  5. Am. Dyest. Rept. v.74 A.H.Zahran;M.B.EI-Hasaby;E.EI-Gendy
  6. J. Macromol. Sci. v.25 A.K.Mukherjee;H.R.Goel
  7. 한국섬유공학회지 v.19 윤병숙;김갑진
  8. 한국섬유공학회지 v.21 김갑진;오창운;윤병숙
  9. 한국섬유공학회지 v.21 박경주;김갑진
  10. U.S. Patent, 2,839,430 E. I. Du Pont de Nemours & Co.
  11. Advances in Urethane Science and Technology v.7 K.C.Frisch;S.L.Reegen
  12. 高分子(日) v.32 S.Yoshida
  13. ACS Symposium Series 270 Reaction Injection Molding G.C.Alfonso;C.Chiappori;S.Razore;S.Russo;J.E.Kresta(ed.)
  14. Reaction Injection Molding W.E.Becker;W.E.Becker(ed.)
  15. J. Polym. Sci., Polym. Phys. Ed. v.24 P.Kolodziej;W.P.Yang;C.W.Macosco;S.T.Wellinghoff
  16. Eur. Polym. J. v.7 J.Sebenda;V.Kouril
  17. J. Polym. Sci. v.10 C.V.Geobel;P.Cefelin;J.Stehlicek;J.Sebenda
  18. J. Macromol. Sci. Chem. v.A6 J.Sebenda
  19. Comprehensive Chemical Kinetics v.15 J.Sebenda;C.H.Bamford(ed.);C.F.H.Tipper(ed.)
  20. Ring-Opening Polymerization H.K.Reimschussel;K.Fritsch(ed.);S.L.Reegen(ed.)
  21. Comprehensive Polymer Science v.3 J.Sebenda;G.C.Eastmond(ed.);A.Ledwith(ed.);S.Russo(ed.);P.Sigwalt(ed.)
  22. Makromol. Chem., Macromol. Symp. v.48;49 S.Russo;E.Biagini;G.Bonta
  23. Polymer v.20 G.Costa;E.Pedemonte;S.Russo;E.Sava