Bulletin of the Korean Chemical Society

  • 제12권3호
  • /
  • Pages.271-273
  • /
  • 1991
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Cationic Polymerization of Electron-Donor Monomers by 1,1,2,2-Tetracyanocyclopropylstyrene, A New Electron-Acceptor

  • Ju-Yeon Lee (Department of Chemistry, Inje University) ;
  • Sung-Ok Cho (Department of Chemistry, Inje University) ;
  • A. B. Padias (C. S. Marvel Laboratories, Department of Chemistry, University of Arizona) ;
  • H. K. Hall, Jr. (C. S. Marvel Laboratories, Department of Chemistry, University of Arizona)
  • 발행 : 1991.06.20
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초록

Poly (N-vinylcarbazole) was obtained spontaneously by 1,1,2,2-tetracyanocyclopropylstyrene(1) in polar solvents such as dichloromethane and acetonitrile at room temperature. The polymerization reactions were faster in more polar solvent and were not proceeded in less polar solvents such as chloroform and diethyl ether. The formation of poly (N-vinylcarbazole) was explained by bond-forming initiation theory, in which the initiating species are zwitterionic tetramethylene intermediates.

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참고문헌

  1. J. Am. Chem. Soc. v.108 T. Gotoh;A. B. Padias;H. K. Hall, Jr.
  2. J. Org. Chem. v.47 H. K. Hall, Jr.;M. Abdelkader;M. E. Glogowski
  3. J. Org. Chem. v.20 M. Abdelkader;A. B. Padias;H. K. Hall, Jr.
  4. J. Org. Chem. v.52 H. K.Hall, Jr.;A. B. Padias;T. -F. Way;B. Bergami
  5. Angew. Chem. Int. Ed. Engl. v.22 H. K. Hall, Jr.
  6. Acc. Chem. Res. v.23 H. K. Hall, Jr.;A. B. Padias
  7. Macromolecules v.24 J. -Y. Lee;A. B. Padias;H. K. Hall, Jr.
  8. Polym. Bull. v.23 J. -Y. Lee;H. K. Hall, Jr.
  9. Arkiv Kemi v.12A no.22 L. Ramberg;S. Wideqvist
  10. Arkiv Kemi v.20B no.4 L. Ramberg;S. Wideqvist
  11. J. Org. Chem. v.28 H. Hart;F. Freeman
  12. Bull. Soc. Chim. Belg. v.98 V. M. Thuy;P. Mattice
  13. J. Am. Chem. Soc. v.18 B. C. Hesse

피인용 문헌

  1. ChemInform Abstract: Cationic Polymerization of Electron Donor Monomers by 1,1,2,2- Tetracyanocyclopropylstyrene, a New Electron Acceptor. vol.22, pp.42, 1991, https://doi.org/10.1002/chin.199142146
  2. A paradigm for the mechanisms and products of spontaneous polymerizations vol.47, pp.24, 2009, https://doi.org/10.1002/pola.23651
  3. Lewis Acid‐Catalyzed [3+4] Annulation of 2‐(Heteroaryl)‐ cyclopropane‐1,1‐dicarboxylates with Cyclopentadiene vol.353, pp.7, 1991, https://doi.org/10.1002/adsc.201000783