알콕사이드로부터 알루미나 미분말의 합성과 그 소결특성

Preparation and Sintering Behavior of Alumina Powders Synthesized from Aluminum Alkoxide

  • 김창은 (연세대학교 요업공학과) ;
  • 이종혁 (연세대학교 요업공학과) ;
  • 이해욱 (연세대학교 요업공학과)
  • 발행 : 1991.07.01

초록

The powder characterization and sintering behavior of alkoxide-derived alumina powders prepared by esterification were investigated. The dried powders were calcined at 700$^{\circ}C$, 900$^{\circ}C$, 1080$^{\circ}C$, 1170$^{\circ}C$ for 1 h. and the resulting crystalline forms were amorphous, {{{{ gamma }} phase, {{{{ theta }}+{{{{ alpha }} phase, and {{{{ alpha }} phase, respectively. The sinterability was best in the case of being calcined at 1170$^{\circ}C$. It was most effective to disperse sintering additive in the initial stage from which acetate was formed. At 1600$^{\circ}C$ for 4 h, 98.5% of relative density was obtained when MgO and Fe2O3 were simultaneously doped, and dense sintered body whose density was near theoretical value was obtained when heating schedule was controlled.

키워드

참고문헌

  1. Ber. Dtsch. Keram. Ges. v.41 Alumina as a Ceramic Material W. H. Gitzen;Dawihl W.(et al.)
  2. Am Ceram. Soc. Bull. v.64 no.12 Sol-Gel Processing of Ceramics and Glass David;W. Johnson Jr.
  3. Chemical Synthesis of Advanced Ceramic Materials Development of the Sol-Gel Process for Alkoxides David Segal
  4. 요업재료의 과학과 기술 v.3 no.3 알루미나의 미세구조 제어 김해두
  5. Trans. Brit. Ceram. Soc. v.80 Fast Firing Microstructural Benefits M.P. Hamer;R.J. Brook
  6. J. Am. Ceram. Soc. v.39 Sintering and Growth of Alpha-Alumina H.P. Caohoon;C.J. Christensen
  7. ibid. v.45 Sintering Alumina: Effect of Atmospheres R.L. Coble
  8. ibid. v.51 no.1 Solubilities of Magnesia, Titania, and Magnesium Titanate in Aluminum Oxide S.K. Roy;R.L. Coble
  9. Mater Sic. Res. v.10 J.G. Peelen
  10. Ceramics Japan v.11 酸化物の 燒結成とその 母鹽: アルシナを 中心とレて S. Kato
  11. Sol-Gel Science Sintering C. Jeffrey Brinker
  12. Acta Metall. v.10 The Impurity-drag Effect in Grain Boundary Motion J.W. Cahn
  13. J. Am. Ceram. Soc. v.66 Effect of MgO Solute on the Kinetics of Grain Growth in Alumina S.J. Bennison;M.P. Harmer
  14. ibid v.72 no.1 Effect of Chemical Inhomogenities on Grain Growth and Microstructure in Alumina R.L. Coble(et al.)
  15. ibid v.56 Effect of Iron Oxide on the Sintering Kinitics of Alumina W.R. Rao;I.B. Culter
  16. Ceram. Bull. v.51 Rate Controlled Sintering of Fine Grained Alumina M.L. Huckabee;H. Palmour Ⅲ