Effect of $MnO_2$ on the Dielectric Hysteresis Loop Characteristics of Pb($Zr_{0.52}Ti_{0.48}$)$O_3$ Ceramics

Pb($Zr_{0.52}Ti_{0.48}$)$O_3$ 세라믹스의 유전이력 특성에 미치는 $MnO_2$의 영향

  • 김종선 (삼성코닝연구소) ;
  • 최병현 (국립공업시험원 도자기시험소) ;
  • 이종민 (국립공업시험원 도자기시험소) ;
  • 윤기현 (연세대학교 요업공학과)
  • Published : 1991.04.01

Abstract

Dielectric hysteresis characteristics of Pb(Zr0.52Ti0.48)O3 ceramics have been investigated as a function of the amount of MnO2 addition ranged from 0.0 wt% in Pb(Zr0.52Ti0.48)O3 ceramics enhanced the dielectric strength, aging effect and remanent polarization, while reduced the coercive field. These results could be explained by the effect of Mn-Vo association due to the substitution of Mn for the (Zr, Ti) site in PZT.

Keywords

References

  1. J. Am. Ceram. Soc. v.65 no.10 Sluggish transition between tetragonal and Rhombohedral Phases of Pb(Zr,Ti)O₃Prepared by Application of Electric Field K. Kakegawa;J. Mohri;S. Shirasaki;K. Takahashi
  2. Ferroelectrics v.46 Some aspects of the physics of Piezoelectric Ceramics V.A. Isupov
  3. J. Am. Ceram. Soc. v.49 no.11 Piezoelectric Properties of Pb(Mg⅛Nb⅜)O₃-PbTiO₃-PbZrO₃Ceramics Modified with Certain Additives H. Ouchi;M. Nishida;S. Hayakawa
  4. Ferroelectrics Letters v.2 Stabilization Effects of Manganese and Cerium on the Properties of PZT Ceramics W.L. Zhong
  5. J. Am. Ceram. Soc. v.52 no.4 Aging in Tetragonal Ferroelectric Barium Titanate R.C. Bradt;G.S. Ansell
  6. J. Kor. Ceram. Soc. v.27 no.2 Effects of $MnO_2$ on the Dielectric and Piezoelectric Properties of $Pb(Zr_{0.52}Ti_{0.48})O_3$ Ceramics J.S. Kim;K.H. Yoon;B.H. Choi;J.O. Park;J.M. Lee
  7. Jpn J. Appl. Phys. v.17 no.4 On the Phenomenon of Morphotropic Tetragonal-rhombohedral Phase Boundary in the Ferroelectric Ceramics L. Hahn;K. Uchino;S. Nomura
  8. J. Appl. Cryst. v.13 The Morphotropic Phase Boundary in PZT Solid Solutions S.A. Mabud
  9. J. Am. Ceram. Soc. v.52 no.5 Lead zirconate-Lead titanate piezoelectric ceramics with iron oxide additives T.B. Weston;A.H. Webster;V.M. McNamara
  10. 粉體およひ粉末治金 v.20 no.7 Breakdown of Lead Zirconate Titanate Ceramics Caused by the Application of Electric Field M. Takahashi;S. Takahashi;T. Ohno;Tsubouch
  11. J. Am. Ceram. Soc. v.49 no.4 Effect of Grain Size on Microcracking in Lead Titanate Ceramics Y. Matsuo;H. Sasaki
  12. J. Appl. Phys. v.30 no.11 Dielectric Breakdown of Porous Ceramics R. Gerson;T.C. Marshall
  13. J. Am. Ceram. Soc. v.46 no.3 Barium Zirconate-Lead Titanate Ferroelectric Ceramics W.R. Bratschun
  14. Jpn. J. Appl. Phys. v.10 no.5 Electrical Resistivity of Lead Zirconate Titanate Ceramics Containing Impurities M. Takahashi
  15. Sol. State Comm. v.11 Thermodynamic Theory of the Morphotropic Phase Transition Tetragonal-rhombohedral in the Perovskite Ferroelectrics L. Benguigui
  16. Ferroelectrics Letters v.44 Low Field Poling of Soft PZTs T.R. Shrout;A. Safari;W.A. Schulze
  17. J. Am. Ceram. Soc. v.53 no.1 Nature Aging in Ferroelectric Ceramics G.H. Jonker
  18. J. Am. Ceram. Soc. v.56 no.2 Effects of Grain Size and Porosity on Electrical and Optical Properties of PLZT Ceramics K. Okazaki;K. Nagata
  19. Ferroelectrics v.40 Principles of Piezoelectric Ceramics for Mechanical Filters H. Thomann;W. Wersing
  20. Jpn. J. Appl. Phys. v.20 no.1 Internal Bias Field Effects in Lead Zirconate Titanate Ceramics Doped with Multiple Impurities S. Takahashi
  21. Ferroelectrics v.41 Effects of Impurity Doping in Lead Zirconate-titanate Ceramics S.Takahashi
  22. J. Phys. Chem. Solids v.47 no.5 The Nature of Domain Stabilization in Ferroelectric Perovskites P.V. Lambeck;G.H. Jonker