Journal of the Korean Society of Clothing and Textiles (한국의류학회지)

The Korean Society of Clothing and Textiles (한국의류학회)
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Adsorption Properties of Uranium on Acrylic Fibers Treated with Hydroxylamine

하이드록실 아민으로 처리한 아크릴 섬유의 우라늄 흡착특성

  • Chin Young Gil (Dept. of Clothing and Textiles, College of Natural Science, Gyeongsang National University) ;
  • Lee Jung Sook (Dept. of Clothing and Textiles, College of Natural Science, Gyeongsang National University)
  • 진영길 (경상대학교 자연과학대학 의류학과) ;
  • 이정숙 (경상대학교 자연과학대학 의류학과)
  • Published : 1990.03.01
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Abstract

Fibrous adsorbents containing amidoxime group which make chelate complexes with uranyl ions are studied for the recovery of uranium from sea water. Acrylic fibers are used as base Polymer. The adsorption properties of uranium are carried out to examine pH effect, concen-tration dependence, adsorption rate, separation, and chelate complex. The results obtained are as follows; 1. Metal capacity of U (VI) ion is in the range of pH $2\~10.2$. Amidoxime group-containing fiber recover U (VI) ions existed in sea water or waste water in extremely small quantities. 3. Using amidoxime group-containing fiber Cu (II) and U (VI) are separated with each other in dilute nitric acid solution (pH 2.3). 4. U (VI) chelate complexes are conformed by tridendate ligands, which are coordinated with one nitrogen and two oxygens onto amidoxime group-containing fiber.

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