한국응용과학기술학회지 (Journal of the Korean Applied Science and Technology)

  • 제7권1호
  • /
  • Pages.49-62
  • /
  • 1990
  • /
  • 1225-9098(pISSN)
  • /
  • 2288-1069(eISSN)
한국응용과학기술학회 (The Korean Society of Applied Science and Technology)
권호 표지
DOI QR코드

DOI QR Code

불소계(弗素系) 계면활성제(界面活性劑)에 관한 연구(硏究)(제(第)1보(報));계면활성(界面活性) 함불소계(含弗素系) N-장쇄(長鎖)아실 크라운 에테르유(類)의 합성(合成)

Studies on the Perfluoro Alkyl Surfactants(I);Synthesis of Surface Active N-Perfluoroacylmono Aza Crown Ethers

  • 손주환 (인하대학교 공과대학 화학공학과) ;
  • 남기대 (충북대학교 공과대학 공업화학과) ;
  • 이승열 (인하대학교 공과대학 화학공학과) ;
  • 소부영 (가 양(주))
  • 발행 : 1990.05.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

In order to synthesize N,N-di-(polyoxyethylene) perfluoroacyl amines and the surface active monoperfluoroacyl aza crown ethers, it is performed as follow. Six of N,N-di(polyoxyethylene) perfluoro acyl amines were synthesized from perfluoroalkanoic acids with ethanol followed by oxyethylation with triethylene glycol mono chloride or tetra ethylene glycol mono chloride and six of N-perfluor acyl monoaza crown ethers by cyclization of corresponding N,N-di(polyoxy ethylene} perfluoro acyl amines with p-toluene suflonic chloride-NaOH/dioxane, p-toluene sulfonyl chloride KOH/dioxane and benzene sulfonic chloride-KOH/dioxane systems.

키워드