DOI QR코드

DOI QR Code

Electrochemical Studies of Oxovanadium(IV) Complex of 2-Amino-1-cyclopentene-1-dithiocarboxylate

  • Young-Jin Kim (Department of Chemistry, Pusan National University) ;
  • Duck-Soo Park (Department of Chemistry, Pusan National University) ;
  • Yoon-Bo Shim (Department of Chemistry, Pusan National University) ;
  • Sung-Nak Choi (Department of Chemistry, Pusan National University)
  • 발행 : 1990.04.20

초록

The redox properties of 2-amino-1-cyclopentene-1-dithiocarboxylate anion (acdc) and its oxovanadium complex, $VO(acdc)_2$ have been investigated in dimethylformamide (DMF) with polarography and cyclic voltammetry. Bis(2-amino-1-cyclopentene-1-dithiocarboxylate) oxovanadium(IV) exhibits two polarographic oxidation waves and two reduction waves in the potential range from +0.50V to - 2.4V vs. the Ag/AgCl (DMF) reference electrode. The second oxidation wave appeared at - 0.08V is found to be reversible and is attributed to the formation of $VO(acdc)_2\;^+$. The first reduction process (at - 0.60V) is also reversible and this reduction process is caused by the electrode process of formation of $VO(acdc)_2$-species. The half wave potential for the reduction, V(IV)$\to$V(III) is more positive for oxovanadium complexes containing sulfur donor atoms than other VO(IV) complexes having oxygen or nitrogen donor atoms.

키워드

참고문헌

  1. BUll. Korean Chem. Soc. v.40 Anal. Chem M.Yokoyama;T.Takeshima
  2. Bull. Korean. Chem. Soc. v.5 Acta Phytopathol. G.M.Matalsky;M.Hamran:B.Bordas
  3. Bull. Korean. Chem. Soc. v.310 Fresenius Z. Anal. Chem. T.Seshadri;A.Kettrup
  4. Bull. Korean. Chem. Soc. v.10 Frog. Inorg. Chem. J. A. McOeverty
  5. Bull. Korean. Chem. Soc. v.11 Prog. Inorg. Chem. D. Coucouvanis
  6. Bull. Korean. Chem. Soc. v.12 ibid. R. Eisenberg
  7. Bull. Korean. Chem. Soc. v.2 Inorg. Chem. Acta Rev. C. K. Jorgensen
  8. Bull. Korean. Chem. Soc. v.25 Top. Curro Chem. J.R.Wasson;G.M.Woltermann;H.J.Stoklosa
  9. Bull. Korean. Chem. Soc. v.102 J. Am. Chem. Soc. T.D.Tullius;W.O.Gillum;R.M.K.Carlson; K.O.Hodgson
  10. Bull. Korean. Chem. Soc. v.72 Proc. Natl. Acad. Sci. USA. R.M.K.Carlson
  11. Bull. Korean. Chem. Soc. v.34 J. Org. Chem. T. Takeshima, M.Yokoyama;T.Imamoto;M.Akano;H.Asaba.
  12. Bull. Korean. Chem. Soc. Nonaqueous solution chemistry R.P.T.Tomkins;O.Popovych
  13. Bull. Korean. Chem. Soc. v.15 Inorg. Chem. T.L.Riechel;L.J.DeHayes;D.T.Sawyer
  14. Bull. Korean. Chem. Soc. v.12;13 lnorg. Chem. A.M.Bond;A.T.Casey;J.R.Thackeray
  15. Bull. Korean. Chem. Soc. v.32 DAEHAN HWAHAK HWOEJEE Y.B.Shim;D.S.Park;S.N.Choi;M.S.Won
  16. Bull. Korean Chem. Soc. v.8 Bull. Korean Chem. Soc. Yoon-Bo Shim;Sung-Nak Choi
  17. Bull. Korean. Chem. Soc. v.14 lnorg. Chem T.L.Riechel;D.T.Sawyer
  18. Bull. Korean. Chem. Soc. v.53 Inorg. Chem. Acta. A.Kapthrkiewicz
  19. Bull. Korean. Chem. Soc. v.20 lnorg. Chem. M.Asri Nawi;T.L.Riechel

피인용 문헌

  1. Synthesis, spectral characterization, crystal structures, and DFT study of three new La(III) 2-amino-1-cyclopentene-1-carbodithioate complexes vol.1248, pp.None, 2022, https://doi.org/10.1016/j.molstruc.2021.131495