한국세라믹학회지 (Journal of the Korean Ceramic Society)

  • 제27권2호
  • /
  • Pages.274-282
  • /
  • 1990
  • /
  • 1229-7801(pISSN)
  • /
  • 2234-0491(eISSN)
한국세라믹학회 (The Korean Ceramic Society)
권호 표지

수산화물과 옥살산염의 열분해에 의한 $SnO_2$미분말의 합성

$SnO_2$ Powder Preparation from Hydroxide and Oxalate and its Characterization

  • 이종흔 (서울대학교 무기재료공학과) ;
  • 박순자 (서울대학교 무기재료공학과)
  • 발행 : 1990.02.01
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초록

SnO2 powder was prepared by hydroxide method and oxalate method. In hydroxide method, the pH dependence of powder characteristics was investigated by using buffer solution. As increasing the pH of solution, SnO2 powder size was decreased because nucleation rate was inctreased by more supersaturation of solution. Also, we found that the powder by our method has larger specific surface area in comaprison with other method. And the degree of agglomeration of precipitate with the change of precipitation temperature was investigated in oxalate method. The SnC2O4 was angular shape precipitate, and the size of the SnC2O4 was increased with the increase of precipitation temperature in methanol solvent.

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참고문헌

  1. J. Am. Cer. Soc. Bull. v.65 no.4 Ceramic Sensor Greg Fisher
  2. Mat. Sci. & Tech. v.1 Semiconductor Gas Sensors P.T. Moseley;B.C. Tofield
  3. 서울대학교 석사학위논문 SnO₂-CuO system의 CO가스 감응성 강진구
  4. J. Electrochem. Soc. v.123 no.9 Physical Properties of SnO₂ Materials. Ⅱ. Electrical Properties Z.M. Zarzebski(et al.)
  5. J. Electrical Mat'ls v.9 no.4 Temperature Dependence of Resistivity of Sn-based Gas Exposed to CO, H. and $C_3H_8$ Gases M. Nitta;S. Ohtani;M. Haradome
  6. Cehmistry Letters Hydrogen Sensitive Gas Detector Using Silver Added Tin(Ⅳ) Oxide N. Yamazoe(et al.)
  7. J. Catalysis v.29 The Catalytic Oxidation of Carbon Monoxide on Tin(Ⅳ) Oxide M.J. Fuller;M.E. Warwick
  8. J. Electrochem. Soc. v.119 no.4 Preparation and Properties of Semiconducting Polycryatalline Tin Oxide C.A. Vincent(et al.)
  9. 日本化學會誌 no.6 含水酸化ススの熱的擧動 金子 正治(等)
  10. セラミツクス製造プロセス 社團法人 日本窯業協會
  11. Dispersion of Powders in Liquids A.G. Walton(et al.)
  12. J. Colloid and Interface Science v.42 no.3 Heterocoagulation in Mixed Oxide Colloidal Dispersion T.W. Healy(et al.)
  13. Introduction to Colloid and Surface Chemistry D.J. Shaw
  14. Principal of Colloid and Surface Chemistry P.C. Heimenz
  15. Zeta Potential in Colloid Science Robert J. Hunter