한국섬유공학회지 (Textile Science and Engineering)

  • 제27권9호
  • /
  • Pages.20-33
  • /
  • 1990
  • /
  • 1225-1089(pISSN)
  • /
  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
권호 표지

옥심 유도체 및 옥심기를 가지는 고분자의 합성과 합성물의 감광특성 (II)

Syntheses of Oxime Derivatives and Polymers Containing Oxime Groups and Their Photosensitive Characteristics (II)

  • 김대진 (서울대학교 공과대학 섬유공학과) ;
  • 홍성일 (서울대학교 공과대학 섬유공학과)
  • Kim, Dae-Jin (Dept. of Textile Eng., College of Eng., Seoul National University) ;
  • Hong, Sung-Il (Dept. of Textile Eng., College of Eng., Seoul National University)
  • 발행 : 1990.09.01

⟨ 이전 논문 다음 논문 ⟩

초록

Benzophenoneoxime(BZPO), ethyloximinocyanoacetate(EOCA), and terephthaldio- xime(TPDO) were synthesized from benzophenone, ethylcyanoacetate, and terephthalaldehyde, respectively. Oxime derivatives were synthesized from 6ximes with benzoylchloride, toluoylchlo-ride, anisoylchloride, ethylchlorocarbonate, and acetylchloride. And oxime monomer, benzophe-none-g-methacryloyloxime (BZMO), was synthesized from methacrylolychloride with BZPO. Photodegradation of oxime derivatives was carried out by the irradiation of W light in which the free radicals, produced during the photodegradation, could initiate vinyl monomer. The relative decomposition efficiency of oxide derivatives was estimated by comparing UV absorbance decreasing at Lmax in function of irradiation time. In addition, polymers containing oxime ester in pendant group, p(BZMO- MMA), were photografted with vinyl monomer. The graft yield of polymers increased with the mole fraction of BZMO.

키워드

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