Modification of Polypropylene by AA/MA Graft Copolymerization

AA/MA그라프트 공중합에 의한 폴리프로필렌의 개질

  • 김영호 (숭실대학교 공과대학 섬유공학과) ;
  • 정도현 (숭실대학교 공과대학 섬유공학과)
  • Published : 1990.07.01

Abstract

The methods of grafting monomer mixture of acrylic acid(Ah)/methacrylic acid(EnA) onto isotactic polypropylene(imP) film by chemical initiation and the effects of grafting conditions on the graft yield have been studied. The AAMk grafted iPP films were characterized with IR, X-ray, and DSC. The surface characteristics such as the surface free energy and the work of adhesion, the frictional electrostatic voltage, and the dyeability with basic dye were also investigated. The AhMk grafted iPP film showed good hydrcphilicity rind the moisture regain of iPP-g- AAMh film increased with the grad yield. The grafted film had good antistatic property and could be dyed with basic dye. The dye uptake increased with the graft yield.

Keywords

References

  1. Polypropylene Fibers Science and Technology M.Ahmed
  2. Production and Applications of Polypropylene O.Pajgrt;B.Reichstadter;F.Sevcik
  3. J. Macromol. Sci. v.A19 no.7 A.K.Mukherjee;B.D.Gupta
  4. J. Appl. Polym. Sci. v.33 M.H.Rao;K.N.Rao
  5. J. Appl. Polym. Sci. v.29 H.T.Lokhande;V.S.Thakar;S.R.Shukla
  6. J. Appl. Polym. Sci. v.30 A.K.Mukherjee;B.D.Gupta
  7. J. Macromol. Sci. v.A14 no.1 P.J.Burchill;D.M.Pinkerton;R.H.Stacewicz
  8. J. Appl. Polym. Sci. v.33 H.T.Lokhande;A.G.Jog;M.D.Teli
  9. Purification of Laboratory Chemicals(2nd Ed.) D.D.Perrin;W.L.F.Armarego;D.R.Perrin
  10. J. Appl. Polym. Sci. v.30 A.K.Mukherjee;B.D.Gupta
  11. Polymer Handbook(3rd Ed.) J.Brandrup;E.H.Immergut
  12. J. Korean Soc. Textile Eng. Chem. v.24 no.1 S.W.Ko;Y.H.Kim
  13. J. Appl. Polym. Sci. v.29 A.K.Gupta;S.N.Purwar
  14. J. Adhesion v.2 D.H.Kaelble
  15. J. Phys. Chem. v.71 Y.Tamai;K.Makuuchi;M.Suzuki
  16. J. Coll. Interf. Sci. v.60 Y.Tamai;T.Matsunaga;K.Horiuchi
  17. J. Appl. Polym. Sci. v.22 T.Matsunaga;Y.Tamai
  18. Dyeing and Chemical Technology of Textile Fibers(5th Ed.) E.R.Trotman