대한화학회지 (Journal of the Korean Chemical Society)

  • 제33권6호
  • /
  • Pages.577-581
  • /
  • 1989
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

활성화시킨 Cu-Zn 과 히드라진을 이용한 방향족 니트로 화합물의 환원반응

Reduction of Aromatic Nitro Group by Activated Cu-Zn-$NH_2NH_2{\cdot}H_2O$ in Ethanol

  • 한병희 (충남대학교 자연과학대학 화학과) ;
  • 신대현 (충남대학교 자연과학대학 화학과) ;
  • 이현노 (충남대학교 자연과학대학 화학과)
  • Byung Hee Han (Department of Chemistry, College of National Science, Chungnam National University) ;
  • Dae Hyun Shin (Department of Chemistry, College of National Science, Chungnam National University) ;
  • Hyun Ro Lee (Department of Chemistry, College of National Science, Chungnam National University)
  • 발행 : 1989.12.20
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초록

황산구리 수용액에 과량의 아연을 반응시켜 만든 구리-아연은 히드라진 존재하에서 방향족 니트로 화합물을 아미노 화합물로 환원시키는데 좋은 촉매작용을 보여주었다. 그러나 지방족 니트로 화합물의 환원반응은 진행되지 않았다.

Activated Cu-Zn by the reaction of aqueous cupric sulfate and excess Zn showed the exceptional catalytic activity for the reduction of aromatic nitro compounds to the corresponding amino compounds in the presence of hydrazine monohydrate in ethanol. But, aliphatic nitro compounds were not reduced to the amino compounds.

키워드

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