Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Studies of the Reactions between P-donors and [$(exo-6-R-\eta^5-2-MeO{\cdot}C_6H_5)Mn(CO)_2NO]PF_6$

  • Taeg Hwan Hyeon (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Taek-Mo Chung (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Young Keun Chung (Department of Chemistry, College of Natural Sciences, Seoul National University)
  • Published : 1989.12.20
Download PDF
⟨ Previous Next ⟩

Abstract

Synthetic studies have been carried out for the addition or substitution of phosphorus nucleophiles to the cation $[(exo-6-R-{\eta}^ {5_-}2-MeO-C_6H_5)Mn(CO)_2NO]PF_6,$ 2. $PPh_3$ reacts with 2 to yield the CO displaced product and $MePPh_2$ attacks the dienyl ring of 2 to yield the phosphonium adduct or the metal to give the CO displaced depending upon the reaction temperatures. Nucleophilic addition of HPPh2 to the dienyl ring of 2 gives a neutral substituted product. $P(OMe)_3$ reacts with 2 to yield a mixture of ring adduct and CO displaced product at room temperature. $At - 20^{\circ}C,\;P(OMe)_3$ attacks the dienyl ring of 2 to give a posphonium adduct, which underwent Arbuzov reaction. This reaction affords a new route to the phosphonate complexes.

Keywords

References

  1. Inorg. Chem. v.18 L. A. P. Kane-Maguire;D. A. Sweigart
  2. J. Organomet Chem. v.256 Y. K. Chung;E. D. Honig;D. A. Sweigart
  3. J. Chem. Soc., Dalton Trans. G. R. Atton;L. A. P. Kane-Maguire
  4. Organometallics v.1 H. S. Choi;D. A. Sweiganrt
  5. Chem. Ber. v.98 G. Drefahl;H. H. Horhold;K. Kunhe
  6. J. Chem. Soc. P. L. Pauson;W. E. Watts
  7. J. Chem. Soc., Dalton Trans. P. Hackett;B. F. G. Johnson;J. Lewis
  8. J. Organomet. Chem. v.308 Y. K. Chung;D. A. Sweigart
  9. J. Organomet. Chem. v.372 T.-H. Hyeon;Y. K. Chung
  10. Organometallics v.1 Y. K. Chung;P. G. Williard;D. A. Sweigart
  11. J. Am. Chem. Soc. v.104 Y. K. Chung;H. S. Choi;D. A. Sweigart;N. G. Connelly
  12. J. Am. Chem. Soc. v.107 Y. K. Chung;D. A. Sweiganrt;N. G. Connelly;J. B. Sheridan
  13. J. Chem. Soc., Dalton Trans. G. R. John;L. A. P. Kane-Maguire;T. I. Odiaka
  14. J. Chem. Soc., Dalton Trans. L. A. P. Kane-Maguire;T. I. Odiaka;S. Turgoose;P. A. Williams
  15. J. Chem. Soc., Dalton Trans. T. I. Odiaka;L. A. P. Kane-Maguire
  16. J. Am. Chem. Soc. v.92 C. A. Tolman
  17. J. Am. Chem. Soc. v.92 C. A. Tolman
  18. Organometallics v.7 S. D. Ittel;J. F. Whitney;Y. K. Chung;P. G. Williard;D. A. Sweigart
  19. Chem. Rev. v.84 T. B. Brill;S. J. Landon
  20. Tetrahedron Lett. A. J. Birch;I. D. Jenkins;A. J. Liepa

Cited by

  1. Synthesis and Reactivity of [(η6-Biphenylene)Mn(CO)3]+ vol.3, pp.1, 1997, https://doi.org/10.1002/chem.19970030113