Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Cross Interaction Constants as a Measure of the Transition State Structure. (Part 10), Mechanism of Reactions between Phenacyl Benzenesulfonates with N,N-Dimethylanilines

  • Published : 1989.10.20
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Abstract

The transition state (TS) structure for the reactions of phenacyl benzenesulfonates with N,N-dimethylanilines (DMA) is investigated using various selectivity parameters, especially with cross-interaction constants, ${\rho}_{ij}$, ${\beta}_{ij}$ and ${\lambda}_{ij}$. The trends in reactivity were similar to aniline series but the TS was found to be somewhat looser than that for aniline series. It was found that the RSP and BEP principle hold within the DMA series but are violated between two different reaction series with DMA and aniline.

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References

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