Bulletin of the Korean Chemical Society

  • 제10권2호
  • /
  • Pages.167-171
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  • 1989
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Kinetic Energy Release in the Fragmentation of tert-Butylbenzene Molecular Ions. A Mass-analyzed Ion Kinetic Energy Spectrometric (MIKES) Study

  • Choe, Joong-Chul (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Kim, Byung-Joo (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Kim, Myung-Soo (Department of Chemistry, College of Natural Sciences, Seoul National University)
  • 발행 : 1989.04.20
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초록

Kinetic energy release in the fragmentation of tert-butylbenzene molecular ion was investigated using mass-analyzed ion kinetic energy spectrometry. Method to estimate kinetic energy release distribution (KERD) from experimental peak shape has been explained. Experimental KERD was in good agreement with the calculated result using phase space theory. Effect of dynamical constraint was found to be important.

키워드

참고문헌

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피인용 문헌

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  2. Analysis of a mass-analysed ion kinetic energy peak profile for a metastable ion decomposition occurring in a collision cell floated at high voltage vol.5, pp.1, 1989, https://doi.org/10.1002/rcm.1290050107
  3. Analysis of a mass-analyzed ion kinetic energy profile. I. Analytical expression for a peak shape at a single kinetic energy release vol.6, pp.2, 1989, https://doi.org/10.1002/rcm.1290060209
  4. Comparative study of kinetic energy release distribution in unimolecular and collision-induced dissociations of molecular ions vol.7, pp.7, 1989, https://doi.org/10.1002/rcm.1290070707
  5. Photodissociation dynamics of the propargyl bromide molecular ion vol.113, pp.5, 1989, https://doi.org/10.1063/1.481973
  6. Kinetic Energy Release in the Loss of Water from n-Propanol Cation vol.27, pp.4, 1989, https://doi.org/10.5012/bkcs.2006.27.4.596
  7. Kinetic Energy Release in the Unimolecular Dissociation of 1-Butanol Cation vol.28, pp.2, 2007, https://doi.org/10.5012/bkcs.2007.28.2.319