Bulletin of the Korean Chemical Society

  • 제10권1호
  • /
  • Pages.57-60
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  • 1989
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Photoaddition Reactions of Alkynes to Quinonoid Compounds

  • Kim Sung Sik (Department of Chemistry, ChonBuk National University) ;
  • Kim Ae Rhan (Department of Chemistry, ChonBuk National University) ;
  • Cho In Ho (Department of Chemistry, ChonBuk National University) ;
  • Shim Sang Chul (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • 발행 : 19890200
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초록

UV irradiation of anthraquinone and diphenylacetylene in benzene gave 1:1 photoadduct (7) and cyclization product (8). The photoreaction of anthrone and diphenylacetylene in dichloromethane afforded the photooxidation products (7, 8, and 9) in air. The photoproduct (7) underwent the cyclization reaction during the purification by the column chromatography (silica gel). When irradiated with 350 nm UV light, the product (11) of benzil reacted with diphenylacetylene to give a photoadduct(12).

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참고문헌

  1. Tetrahedron Letters v.31 D. Bryce-Smith;G. I. Fray;A. Gilbert
  2. Tetrahedron Letters H. E. Zimmerman;L. Craft
  3. Tetrahedron Letters v.47 D. Bryce-Smith;A. Gilbert
  4. Tetrahedron Letters S. P. Pappas;B. C. Pappas
  5. J. Chem. Soc. (C) D. Bryce-Smith;A. Gilbert;H. G. Johnson
  6. J. Chem. Soc. (C) J. A. Barltrop;B. Hesp
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  9. J. Org. Chem. v.45 no.4 E. A. Fehnel;F. C. Brokaw
  10. J. Am. Chem. Soc. v.104 R. Outcalt;F. Geiser;S. K. Gee;W. Brabender;L. Yerino, Jr.;T. T. Conrad;G. A. Tharp
  11. Bull. Chem. Soc. Jpn. v.58 no.5 A. Mori;H. Takeshida
  12. Bull. Korean Chem. Soc. v.8 no.4 Sung Sik Kim;Dong Yeol Yoo;In Ho Cho;Sang Chul Shim
  13. Bull. Korean Chem. Soc. v.9 no.4 Sung Sik Kim;Dong Yeol Yoo;In Ho Cho
  14. Bull. Korean Chem. Soc. v.8 no.5 Sung Sik Kim;Yong Joon Yoon;In Ho Cho;Sang Chul Shim

피인용 문헌

  1. ChemInform Abstract: Photoaddition Reactions of Alkynes to Quinonoid Compounds. vol.20, pp.31, 1989, https://doi.org/10.1002/chin.198931072