가황(加黃)고무의 물리적(物理的) 성질(性質)에 미치는 가교구조(架橋構造)의 영향(影響)

The Effect of Crosslink Structures on the Physical Properties of Carbon Black Filled NR and SBR Vulcanizates

The mono-, di- and polysulfidic concentrations of the carbon black filled NR and SBR vucanizates which have different cure systems were determined. The n-decane was used as a swelling solvent. The propane-2-thiol and hexane thiol were used as specific chemical probes to cleavage the chemical crosslinks such as di- and polysulfide. In order to understand the effect of crosslink structure on the physical properties of vulcanizates, the tensile properties, fatigue failure, heat build up, compression set and viscoelastic properties were measured. From the results, the significant relationships between crosslink sturctures and physical properties, especially a gins resistance were obtained. Therefore, the better performances of the product can be satisfied by using the interpretations and approaches in this study.