대한화학회지 (Journal of the Korean Chemical Society)

  • 제32권6호
  • /
  • Pages.549-556
  • /
  • 1988
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

리간드 N-Benzylisonitrosoacetylacetone Imine의 구조

The Structure of Ligand, N-benzylisonitrosoacetylacetone Imine

  • Byung Kyo Lee (Department of Materials Science and Engineering, Kyungpook National Universtiy) ;
  • Dae Sub O (Department of Chemistry, Kyungpook National University) ;
  • Heung Lark Lee (Department of Chemistry, Kyungpook National University)
  • 발행 : 1988.12.20
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초록

이미 합성된 N-benzylisonitrosoacetylacetone $imine^1$의 유기용매내에서의 구조변화를 측정하기 위하여 여러가지 유기용매에서의 핵자기공명스펙트럼 및 Carbon-13 핵자기공명 DEPT 스펙트럼 등의 분광학적인 자료를 이용하였다. 그 결과 이 시약은 monoxime의 일종으로 용매 중에서 syn- 형과 anti- 형의 기하이성질체가 공존하고 있으며 각각이 토우토메리 현상을 일으키고 있다.

In order to study the changes for the structure of N-benzylisonitrosoacetylacetone imine synthesized already in organic solution, nmr and carbon-13nmr DEPT spectra of the this reagent have been studied. Based on the present studies, it is suggested that this reagent is monoxime having syn- and anti-form isomers and has tautomers in solution respectively.

키워드

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