1,2,4-Triazine Ⅰ ; 6-Oxo-1,6-dihydro-1,2,4-triazine 유도체의 Tautomeric 평형에 관한 연구

1,2,4-Triazine Ⅰ ; Tautomerism in Substituted 6-Oxo-1,6-dihydro-1,2,4-triazines

  • 이재근 (경북대학교 자연과학대학 화학과) ;
  • 박무덕 (경북대학교 자연과학대학 화학과) ;
  • 이동엽 (경북대학교 자연과학대학 화학과) ;
  • 김우식 (경북대학교 공과대학 고분자공학과)
  • Jae-Keun Lee (Department of Chemistry, College of Natural Science, Kyungpook University) ;
  • Moo-Duk Park (Department of Chemistry, College of Natural Science, Kyungpook University) ;
  • Dong-Yeob Lee (Department of Chemistry, College of Natural Science, Kyungpook University) ;
  • Woo-Sik Kim (Department of Polymer Science, College of Engineering, Kyungpook National University)
  • 발행 : 1988.08.20

초록

잘 알려져 있지 않는 6-oxo-1,6-dihydro-1,2,4-triazine 유도체 합성을 시도하였다. 가능한 각 tautomer의 model화합물을 합성하고 이들의 UV Spectra를 물과 alcohol용매 상에서 비교하여 tautomeric 평형을 검토하였다. 기대했던 상당량의 6-hydroxy tautomer는 관찰되지 않고 대부분 6-oxo-tautomer로 용액상태에서 존재함을 알았다.

Synthesis of 6-oxo-1,6-dihydro-1,2,4-triazine derivatives was tried. The model compounds of the possible tautomers were synthesized. The tautomeric equilibrium of 6-oxo-1,6, dihydro-1,2,4-triazine derivatives was determined by comparing their UV spectra and those of model compounds. 6-oxo-tautomer was exclusively detected in water and alcohol solutions without observation of the expected 6-hydroxy tautomers.

키워드

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