Bulletin of the Korean Chemical Society

  • 제9권5호
  • /
  • Pages.275-280
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  • 1988
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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A Study on the High Resolution Infrared Spectra of an Asymmetric Top Molecule $CF_2Cl_2$

  • 발행 : 1988.10.20
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초록

The high resolution IR spectra of freon-12($CF_2Cl_2$) for the bands of 671cm$^{-1},\;922cm^{-1},\;1102cm^{-1},\;and\;1160cm^{-1}$ were taken and the rotational vibrational analysis has been carried out. The band types of $671cm^{-1}\;and\;1102cm^{-1}$ were confirmed to be A and those of $922cm^{-1}\;and\;1160cm^{-1}$ were confirmed to be B. The theoretically synthesized spectra were matched with the experimentally obtained spectra to get some informations of the molecular rotational behavior as well as the overall band shape of the spectra.

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참고문헌

  1. Physical Review v.59 H. H. Nielsen
  2. J. Chem. Physic v.15 G. W. King
  3. J. Chem. Physic v.19 P. A. Giguere
  4. J. Chem. Physic v.18 H. C. Allen;P. C. Cross
  5. J. Chem. Physic v.15 R. M. Hainer;G. W. King
  6. J. Am. Chem. Soc. v.70 H. W. Thompson;R. B. Temple
  7. J. Am. Chem. Soc. v.58 L. O. Brockway
  8. J. Am. Chem. Soc. v.58 L. O. Brockway
  9. Molecular Vib-Rotors: The Theory and interpretation of high resolution infrared spectra H. C. Allen;P. C. Cross
  10. J. Chem. Physic v.11 G. W. King;R. M. Hainer;P. C. Cross
  11. J. Chem. Physic v.12 P. C. Cross;R. M. Hainer;G. W. King
  12. J. Chem. Physic v.59 R. S. Mulliken
  13. J. Chem. Physic v.22 H. H. Claassen
  14. J. Mol. Spec. v.91 J. Harold;M.-C. Mireile
  15. J. Mol. Spec. v.117 T. Gerhard;J. Harold

피인용 문헌

  1. The structure of solid dichlorodifluoromethane CF2Cl2by powder neutron diffraction vol.197, pp.1, 1988, https://doi.org/10.1524/zkri.1991.197.1-2.121
  2. High-resolution FTIR–jet spectroscopy of CCl2F2 vol.90, pp.8, 1988, https://doi.org/10.1039/ft9949001055