Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of Diaryl $\alpha$-Diketones via Palladium Catalyzed Double Carbonylative Homo Coupling of Aryl Iodides with Carbon Monoxide

  • Kim Jin Il (Department of Industrial Chemistry, Hanyang University) ;
  • Kim Nam Jung (Department of Industrial Chemistry, Hanyang University) ;
  • Ryu Cheol Mo (Department of Chemical Enginnering, National Kyonggi Open University)
  • 김진일 (한양대학교 공과대학 공업화학과) ;
  • 김남정 (한양대학교 공과대학 공업화학과) ;
  • Published : 1988.02.20
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Abstract

Symmetrical diaryl ${\alpha}-diketones$ were synthesized in moderately good yields through the palladium catalyzed reaction of aryl iodides with carbon monoxide. The reaction was tolerant of a wide variety of fuctionalities($OCH_3,\;CH_3,\;NO_2,\;OH,\;COOH$) on the aryl iodide. On the other hand, the similar reaction of aryl bromides or chlorides with carbon monoxide did not proceed.

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Cited by

  1. Double carbonylation and beyond: systems at work and their organometallic models vol.2003, pp.6, 1988, https://doi.org/10.1039/b209103h