Bulletin of the Korean Chemical Society

  • 제9권1호
  • /
  • Pages.13-15
  • /
  • 1988
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Halogenation of Resorcinol Derivatives

  • 백승화 (원광대학교 자연과학대학 화학과)
  • 발행 : 1988.02.20
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초록

Several types of resocinols have been monobrominated in the ring in good yields with sodium bromide in the presence of 18-crown-6 on oxidation with m-chloroperbenzoic acid. Monoiodination takes place with 2'-(1-methylcyclohexen-3-yl)-5-(1,1-dimethylheptyl )-resocinol when sodium iodide is employed. This new reagent system, MX/18-crown-6/m-CPBA (M =$K^+, Na^+, X = Br^-, I^-X$ ), effects the regiospecific halogenation of activated aromatic ring over olefinic double bond.

키워드

참고문헌

  1. Synthesis G. A. Olah;Y. D. Vankar;M. Arvanaghi;G. K. S. Prakash
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  7. Doctoral thesis, The Hebrew Univ. of Jerusalem S. H. Baek
  8. Doctoral thesis, The Hebrew Univ. of Jerusalem M. Srebnik
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  15. J. Chem. Soc. Perkin Trans. I M. Srebnik;R. Mechoulam;I. Yona

피인용 문헌

  1. ChemInform Abstract: Halogenation of Resorcinol Derivatives. vol.19, pp.35, 1988, https://doi.org/10.1002/chin.198835108