각종 탈검제에 의한 식물성 기름의 탈검효과

Degumming Effect on Vegetable oil of Degumming agent

탈검제로 인산 및 초산, 구연산, 수산, 질산, 붕산 등 6종을 평지씨 기름과 대두유에 적용시킨 결과 수산을 사용하여 인산과 거의 동일한 탈검 효과를 얻을 수 있었다. 즉, 평지씨 기름에서 85% 인산 처리군과 5.10% 수산 처리군의 탄산유내의 잔류 비누물질과 인함량, 탈색유에서의 색상, 탈취유의 과산화물값, trans 지방산 함량 등은 유사한 결과를 나타내었다. 대두유에서도 동일한 결과를 얻었으므로 탈검제로서 인산 대신 수산을 사용할 수 있음을 확인하였다. 한편 85% 인산처리군과 10% 수산처리군으로부터 얻어진 폐수를 분석한 결과 특히 BOD, COD 등에서 현격한 차이를 보였으며 침전분리 및 화학처리한 결과 인산 처리군은 수산 처리군에 비하여 처리시약 요구량 및 처리시간이 각각 3배, 1.7배로 차이가 극심하였다. 따라서 이들 식물성 기름에서 인산대신 수산을 사용하여 동일한 탈검효과를 얻을 수 있었을 뿐만 아니라 폐수 처리도 개선할 수 있었다.

The almost similar degumming effect was obtained by using oxalic acid instead of phosphoric acid, which also improves waste-water treatment. At this point, solution of Phosphoric, Acetic, Citric, Oxalic, and Nitric acid were used for degumming of rapeseed and soybean oil. Compared with Phosphoric(PA) and Oxalic acid(OA) were showed a simillar degumming effect in these vegetable oils. In rapeseed oil of 85% PA treating group and 5,10% OA fretting group, residual soap and phosphorus content in neutralized oil, color in bleached oil, and peroxide value and fatty acid content in deodrized oil were showed to simillar result. Soybean oil as well as rapeseed oil were showed to similar result. As a result, we could comfirmed substitutive possibility, which change PA into OA as a degumming agent. In the other hand, waste waters were obtained from 55% PA treating group and 10% OA treating group. Analytical result for this waste waters has showed a wide difference, especially in the BOD and COD. The amount of treating agents and time required in the precipitation seperation and chemical treatment each 3 and 1.7 times, which is PA treating group than OA treating group. We have investigated both the simillar degumming effect by OA solution and an alternative the pollution program means of a chemical treatment process is not possible.