물 또는 Propylene Glycol 용매계에서 D-Glucose와 DL-Alanine 또는 DL-$\alpha$- Aminoutyric acid와의 마이야르 반응에 의한 휘발성 화합물의 생성

Formation of Volatile Compounds from Maillard Reaction of D-Glucose and DL-Aranine or DL-?? -Aminobutyric acid in Water or Propylene Glycol Solution

  • 김영회 (한국인삼연초연구소 화학부) ;
  • 김옥찬 (한국인삼연초연구소 화학부) ;
  • 이정일 (한국인삼연초연구소 화학부) ;
  • 양광규 (한국인삼연초연구소 화학부)
  • 발행 : 1988.11.01

초록

The volitile compounds Produced from the Maillard reaction of D-glucose and DL-alanine or DL-$\alpha$-aminobutyric acid using water or propylene glycol as a reaction amdeum were analysed by gas chromatofiraphy and mass spectrometry. From two kinds of reaction products in water 18 compounds were identified. The major compounds in a reaction product of glucose with alanine were 5-hydroxy methyl-2-furfural, 2-acetyl pyrrole and 2-formyl-5-methyl pyrrole, and those in a reaction product of glucose with $\alpha$-aminobutyric acid were 2-ethyl crotonaldehyde and 2-methyl-3, 5-dihydroxy-4H-pyran-4-one including the above 3 compounds. From two kinds of reaction products in propylene glycol solution, 35 compounds were identified. The major compounds in a reaction product of glucose with alanine were alkyl pyraainef, 2-methyl furfuryl alcohol and 2-acetyl pyrrole, and those in a reaction product of glucose with $\alpha$-aminobutyric acid were propionaldehyde PGA, 2-ehtyl crotonaldehyde, 2-acetyl pyrrole and 2-acetyl-5-ethyl furan.

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