측쇄에 전 방향족 올리고 아미드를 가지는 고분자의 합성 및 그 열적 성질

Syntheses and Thermal Properties of Polymers Having Wholly Aromatic Oligoamides as Side Chains

  • 전승범 (서울대학교 공과대학 섬유공학과) ;
  • 박원호 (서울대학교 공과대학 섬유공학과, 서울대학교 공과대학 섬유공학과) ;
  • 하완식
  • 발행 : 1988.02.01

초록

New polymers which have wholly aromatic oligoamides as side chains were synthesized. Poly(N-phenyl acrylamide) (PPA) and poly(N-acryloyl-$\rho$-aminobenzanilide) (PBA) were prepared by the reaction of poly(acrylor chloride) with aniline and $\rho$-aminobenzanilide, respectively. The thermal properties of both polymers were examined by differnetial scanning calorimetry and thermogravimetry. It was found that PPA and PBA were in partly crystalline form, but no melting point could be detected. The Thermal property of the polymers was superior to that of poly(acrylic acid).

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