PVDF 필름의 초전특성에 공간전하가 미치는 영향

Effect of Space Charge on the Properties of Pyroelectricity of PVDF Films

In order to investigate the mechanism of pyroelectricity on polyvinylidene fluoride film, the observations were carried out on the characteristics of infrared spectra, thermally stimulated current and pyroelectric current. As the results obtained from the study, it was concluded that the origin for thermally stimulated current exhibited above room temperature can be attributed to hole injected from anode during poling process. Futhermore it is clarified also that the origin of pyroelectricity observed on the specimen concerned is to spontaneous polarization of CF dipole attached to molecular chain segment, however, the fraction of spontaneous polarization is largely influenced by the amount of hole injected from anode.