유기초음파화학·초음파가 $BaMnO_4$$KMnO_4-CuSO_4{\cdot}5H_2O$를 이용한 알코올의 산화반응에 미치는 영향

The Effects of Sonic Waves on the Oxidation Reaction of Alcohols Using $BaMnO_4\;and\;KMnO_4-CuSO_4{\cdot}5H_2O$

  • 유의상 (충남대학교 자연과학대학 화학과) ;
  • 신대현 (충남대학교 자연과학대학 화학과) ;
  • 한병희 (충남대학교 자연과학대학 화학과)
  • Eui Sang Ryoo (The Department of Chemistry, College of Natural Science, Chungnam National University) ;
  • Dae Hyun Shin (The Department of Chemistry, College of Natural Science, Chungnam National University) ;
  • Byung Hee Han (The Department of Chemistry, College of Natural Science, Chungnam National University)
  • 발행 : 1987.08.20

초록

초음파(50KHz)가 상온 상압하에서 $BaMnO_4$$KMnO_4-CuSO_4{\cdot}5H_2O$를 이용한 1차, 벤질, 2차 알코올의 알데히드 및 케톤 생성반응을 가속 완결시켰으며 고속교반이나 가열 환류반응보다 높은 산화율을 주었다.

Sonic waves (50KHz) was accelerated the oxidation reaction of primary, benzyl and secondary alcohol with $BaMnO_4\;and\;KMnO_4-CuSO_4{\cdot}5H_2O$ to give the corresponding aldehyde and ketone at $30^{\circ}C/1$ atm. in high yields compared to stirring or refluxing condition.

키워드

참고문헌

  1. J. Accoustic. Soc. Am. v.19 H. B. Briggs;J. B. Johnson;W. P. Mason
  2. Phys, J. Appl. v.19 J. C. Fisher
  3. Science R. B. Linda
  4. J. Am. Chem. Soc. v.61 E. N. Harvey
  5. Ultrasound El'Piner
  6. Izd. Akad. Nauk. SSSR Application of Ultrasound L. D. Rozenberg
  7. Organometallics v.2 B. H. Han;P. Boudjouk
  8. J. Org. Chem. v.47 B. H. Han;P. Boudjouk
  9. J. Chem. Soc., Chem. Commun. R. Neumann;Y. Sasson
  10. J. Org. Chem. B. H. Han;P. Boudjouk
  11. J. Org. Chem. v.51 no.14 B. H. Han;P. Boudjouk
  12. Organometallics B. H. Han;P. Boudjouk
  13. Organometallics v.5 no.6 B. H. Han;P. Boudjouk
  14. Bull. Korean Chem. Soc. v.6 B. H. Han;D. H. Shin;S. Y. Cho
  15. Bull. Korean Chem. Soc. v.6 B. H. Han;D. H. Shin;S. Y. Cho
  16. Daean Hwahak Hwoejee v.29 no.5 B. H. Han
  17. Daean Hwahak Hwoejee v.29 B. H. Han
  18. Daean Hwahak Hwoejee v.30 B. H. Han
  19. Progress in Chemistry and Chemical Industry v.23 B. H. Han
  20. Chungnam J. Sciences v.12 B. H. Han;M. G. Baek
  21. Adv. Organomet. Chem. v.25 K. S. Suslick
  22. J. Organomet. Chem. v.307 P. H. Yang;Y. T. Lin
  23. Heterocycles v.23 R. S. Verma;G. W. Kabalka
  24. Tetrahedron Lett. v.27 J. Einhorn;J. L. Luche
  25. J. Organomet. Chem. v.302 no.C13 S. V. Ley;C. R. Low;A. D. White
  26. J. Chem. Soc. Chem. Commun. A. K. Bose;K. Gupta;M. S. Manhas
  27. Syn. Commun. v.16 no.7 P. Boudjouk;J. H. So
  28. Tetrahedron v.41 T. J. Mason;J. P. Lorimer;B. P. Mistry
  29. J. Org. Chem. v.50 C. Petrier;J. C. S. Barbosa;C, Dupuy;J. L. Luche
  30. Bull. Chem. Soc. Japan v.58 J. Yamashita;Y. Inoue;T. Kando;H. Hashimoto
  31. Synthesis J. Bremman;H. S. Hussain
  32. Chem. Lett. T. Ando;T. Kawate;J. Ichihara;T. Hanafusa
  33. Synthesis v.65 A. J. Fatiadi
  34. Reagent for Organic Syntheses v.1 L. F. Fieser;M. Fieser
  35. J. Am. Chem. Soc. v.98 G. Cainelli;G. Cardilo;M. Orena;S. Sandri
  36. Can. J. Chem. v.50 J. M. Lalancette;G. Rolline P.;P. Dumas
  37. J. Org. Chem. v.35 A. C. Louis
  38. J. Am. Chem. Soc. v.99 S. S. Regen;C. Koteel
  39. Synthesis E. Santaniello;F. Pinti;A. Monsocchi
  40. Tetrahedron Lett. v.35 R. P. Singh;H. N. Subbarav;S. Dev
  41. Tetrahedron Lett. M. Y. Sheikh
  42. Tetrahedron Lett. R. J. Auddette;J. W. Quail;P. J. Smith
  43. Tetrahedron Lett. v.27 K. S. Kim;Y. H. Song;N. H. Lee;C. S. Hahn
  44. Tetrahedron Lett. H. Firouzabadi;E. Ghaderi
  45. Bull. Chem. Soc. Japan v.56 H. Firouzabadi;Z. Mostafavipoor
  46. J. Org. Chem. v.44 F. M. Menger;C. See
  47. J. Am. Chem. Soc. v.105 D. G. Lee;N. A. Noureldin
  48. J. Am. Chem. Soc. v.94 L. J. Sam;H. E. Simmons
  49. Chem. Lett. T. Sitazume;N. Ishikawa