DOI QR코드

DOI QR Code

Excitation of Fluorescent Aromatic Hydrocarbons in Chemiluminescence Reactions of Bis (2, 4, 6-trichlorophenyl) oxalate and Hydrogne Peroxide

  • Published : 1987.12.20

Abstract

The excitation mechanism of fluorescers for the chemiluminescence arising from the reaction between bis(2, 4, 6-trichlorophenyl) oxalate (TCPO) and hydrogen peroxide in the presence of fluorescent polycyclic aromatic hydrocarbons has been studied. A key intermediate is generated from the reaction of TCPO with $H_2O_2$ and then the excitation of fluorescer.

Keywords

References

  1. Analyst v.108 L. J. Kricka;G. H. G. Thorpe
  2. Anal. Chim. Acta v.115 G. Scott;W. R. Seitz;J. Ambrose
  3. J. Am. Chem. Soc. v.89 M. M. Rauhut(et al.)
  4. Anal. Chem. v.56 K. W. Sigvardson;J. M. Kennish;J. W. Birks
  5. Anal. Chem. v.55 K. W. Sigvardson;J. W. Birks
  6. Anal. Chem. v.55 K. Honda;J. Sekino;K. Imai
  7. Anal. Chim. Acta v.97 P. A. Sherman;J. Holtzbecher;D. E. Ryan
  8. Mol. Photochem. v.6 P. Lechtken;N. J. Turro
  9. J. Am. Chem. Soc. v.108 F. J. Alvarez(et al.)
  10. J. Chem. Soc., Faraday Trans. 2 v.80 C. L. R. Catherall;T. F. Palmer;R. B. Cundall
  11. Acc. Chem. Res. v.2 M. M. Rauhut
  12. Prog. Org. Chem. v.8 F. McCapra
  13. J. Chem. Educ. v.51 A. G. Mohan;N. J. Turro
  14. Elements of Organic Photochemistry D. D. Cowan;R. L. Drisko
  15. Principles of Fluorescence Spectroscopy J. R. Lakowicz
  16. J. Am. Chem. Soc. v.85 E. S. Pysh;N. C. Yang