Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Chromatographic Behavior of Cryptand[2,2] Modified Resin on Metal Cations

  • Published : 1987.10.20
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Abstract

Cryptand[2,2] was grafted to low crosslinked styrene-divinylbenzene copolymer by substitution reaction with chloromethylated styrene-divinylbenzene copolymer. This resin was stable in concentrated acid and base, and showed a good resistance to heat. The pH, time, and concentration dependence of the adsorption of metal ions by this resin were studied. Studies on the chromatographic separation of lanthanides, $Cu^{2+}$ and $UO_2^{2+_2}$ were also carried out with various eluents. These studies demonstrate that this resin has the applicability to the preconcentration and separation of metal ions.

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