Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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1-Methylimidazolium Chlorochromate. A New Efficient Oxidizing Agent for Oxidation of Alcohols and Oxidative Cleavage of Oximes

  • Kim, Sung-Gak (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Chang, Heung (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • Published : 1987.06.20
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Abstract

1-Methylimidazolium chlorochromate was prepared by the addition of 1-methylimidazole into a solution of chromic trioxide in 6M hydrochloric acid and obtained in high yield as bright yellow crystalline solids. The reagent was found to be very effective for the oxidation of alcohols and the oxidative cleavage of oximes to the corresponding carbonyl compounds.

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References

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Cited by

  1. ChemInform Abstract: 1‐Methylimidazolium Chlorochromate. A New Efficient Oxidizing Agent for Oxidation of Alcohols and Oxidative Cleavage of Oximes. vol.18, pp.52, 1987, https://doi.org/10.1002/chin.198752197
  2. γ-PICOLINIUM CHLOROCHROMATE (γ-PCC): A NEW AND EFFICIENT REAGENT FOR THE OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS vol.31, pp.8, 2001, https://doi.org/10.1081/scc-100104013
  3. Ethylenebis(N-Methylimidazolium) Chlorochromate (EBMICC): A New Selective and Mild Reagent for Oxidation of Alcohols, Hydroquinones and Trimethylsilyl Ethers vol.55, pp.1, 2008, https://doi.org/10.1002/jccs.200800036
  4. Ionic Liquid Oxidant for Efficient and Selective Oxidation of Benzylic Alcohols vol.41, pp.12, 1987, https://doi.org/10.1080/00397911.2010.492077