Abstract
The out-of-plane bending, vibrational-rotational FT-IR spectra of dichloroborane molecule were analyzed. The band centers are 785.992, 785.723, 647.217, and 646.997 $cm^{-1}$ and centrifugal distortion constants are $2.2{\times}10^{-6},\;5.5{\times}10^{-6},\;0.2{\times}10^{-6}$, and $0.7{\times}10^{-6}cm^{-1}$ for $H^{11}B^{35}Cl_2$, $H^{11}B^{35}Cl^{37}Cl$, $D^{11}B^{35}Cl_2$, and $D^{11}B^{35}Cl^{37}Cl$, respectively. The theoretical spectrum of $D^{11}B^{36}Cl_2$ was plotted to conform the molecular constants and the rotational constants for the first excited vibrational state of this molecule were A' = 1.165932, B' = 0.106166, and C' = 0.097229 $cm^{-1}$. The calculated spectra were in good agreement with the observed spectra.
