Bulletin of the Korean Chemical Society

  • 제8권2호
  • /
  • Pages.111-114
  • /
  • 1987
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Simulation of Temperature-Dependent EPR Spectra of Mixed-Valence Copper (II)-Copper (I)-Complexes

  • 발행 : 1987.04.20
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초록

Temperature-dependent, solution EPR spectra of two mixed-valence copper(II)-copper(I) complexes have been simulated by using modified Bloch equations. The transition probability for the intramolecular electron transfer is determined from the simulation. The transition probabilities have been fitted to the Arrhenius equation to derive the activation energies. The transition probability also varies according to the solvent used.

키워드

참고문헌

  1. Mixed-Valence Compounds. Theory and Applications in Chemistry, Physics, and Biology D. B. Brown(ed.)
  2. Copper Proteins E. I. Solomon;T. G. Spiro(ed.)
  3. Inorg. Nucl. Chem. Lett. v.12 A. W. Addison
  4. J. Am. Chem. Soc. v.101 R. R. Gagne;C. A. Koval;T. J. Smith;M. C. Cimolino
  5. J. Am. Chem. Soc. v.105 R. C. Long;D. N. Hendrickson
  6. J. Chem. Phys. v.21 H. S. Gutowsky;D. W. McCall;C. P. Slichter
  7. J. Chem. Phys. v.21 H. S. Gutowsky;A. Saika
  8. J. Chem. Phys. v.44 R. Wilson;D. Kivelson
  9. Introduction to Magnetic Resonance A. Carrington;A. D. McLachlan
  10. Introduction to Magnetic Resonance A. Carrington;A. D. McLachlan
  11. J. Chem. Soc. (A) S. Antosik;N. D. Brown;A. A. McConnell;A. L. Porte
  12. Mechanisms of Inorganic Reactions(2nd ed.) F. Basolo;R. G. Pearson
  13. Bull. Korean Chem. Soc. v.7 C. W. Lee;H. So

피인용 문헌

  1. Coexistence of one-electron- and monoprotonated two-electron-reduced species of the K5[PMo2VW9O40] · 24H2O heteropolyoxometalate identified by EPR vol.20, pp.3, 1987, https://doi.org/10.1007/bf03162286
  2. Acceptor defect-participating magnetic exchange in ZnO : Cu nanocrystalline film: defect structure evolution, Cu-N synergetic role and magnetic control vol.3, pp.6, 2015, https://doi.org/10.1039/c4tc01958j