Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Simulation of Temperature-Dependent EPR Spectra of Mixed-Valence Copper (II)-Copper (I)-Complexes

  • Published : 1987.04.20
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Abstract

Temperature-dependent, solution EPR spectra of two mixed-valence copper(II)-copper(I) complexes have been simulated by using modified Bloch equations. The transition probability for the intramolecular electron transfer is determined from the simulation. The transition probabilities have been fitted to the Arrhenius equation to derive the activation energies. The transition probability also varies according to the solvent used.

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References

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