Bulletin of the Korean Chemical Society

  • 제7권5호
  • /
  • Pages.357-362
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  • 1986
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Synthesis of Some Conjugated Polyynes

  • Shim, Sang-Chul (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Lee, Tae-Suk (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • 발행 : 1986.10.20
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초록

Several aryl substituted 1,3,5-hexatriynes were synthesized by the use of aryl containing trimethylsilylated 1,3-butadiyne intermediates. 1-Phenyl-1,3,5-heptatriyne, one of the naturally occurring phototoxic conjugated polyacetylenes, and 1-(1'-naphthyl)-1,3,5-heptatriyne were prepared by the use of 1-trimethylsilyl-1,3-pentadiyne which is a very stable precursor for the 1,3-pentadiyne at room temperature.

키워드

참고문헌

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피인용 문헌

  1. Photoreaction of 1-(1-naphthyl)-1,3-butadiynes with methanol vol.53, pp.3, 1986, https://doi.org/10.1016/1010-6030(90)87136-y
  2. IDENTIFICATION AND CHARACTERIZATION OF THE MAJOR PHOTOADDUCTS FORMED BETWEEN 1‐PHENYL‐1,3,5‐HEPTATRIYNE AND UNDECYLENIC ACID METHYL ESTER vol.55, pp.3, 1992, https://doi.org/10.1111/j.1751-1097.1992.tb04245.x
  3. PHOTOCHEMISTRY OF CONJUGATED POLYACETYLENES: [2+2] PHOTOCYCLOADDITION OF l‐PHENYL‐l,3,5‐HEXATRIYNES WITH SOME OLEFINS vol.58, pp.2, 1986, https://doi.org/10.1111/j.1751-1097.1993.tb09542.x