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Synthesis of Some Conjugated Polyynes

  • Shim, Sang-Chul (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Lee, Tae-Suk (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • Published : 1986.10.20

Abstract

Several aryl substituted 1,3,5-hexatriynes were synthesized by the use of aryl containing trimethylsilylated 1,3-butadiyne intermediates. 1-Phenyl-1,3,5-heptatriyne, one of the naturally occurring phototoxic conjugated polyacetylenes, and 1-(1'-naphthyl)-1,3,5-heptatriyne were prepared by the use of 1-trimethylsilyl-1,3-pentadiyne which is a very stable precursor for the 1,3-pentadiyne at room temperature.

Keywords

References

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Cited by

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