Bulletin of the Korean Chemical Society

  • 제7권2호
  • /
  • Pages.106-108
  • /
  • 1986
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Absolute Configuration of p-Substituted Benzoates of Panaxynol

  • Shim, Sang-Chul (Department of Chemistry, The Korea Advanced Institute of Science and Technology) ;
  • Koh, Hun-Yeong (Department of Chemistry, The Korea Advanced Institute of Science and Technology) ;
  • Chang, Suk-Ku (Department of Chemistry, The Korea Advanced Institute of Science and Technology) ;
  • Moon, Soon-Ku (Department of Chemistry, Dongguk University) ;
  • Min, Tae-Jin (Department of Chemistry, Dongguk University)
  • 발행 : 1986.04.20
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초록

Exciton chirality method was applied for the determination of absolute configuration of panaxynol, a poly-yne compound from Panax ginseng roots for the first time. The circular dichroic spectra of panaxynol benzoates show the negative chirality at ${\lambda}_{ext}$, indicating the S configuration of C-3 chiral center.

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참고문헌

  1. J. Pharmac. Soc. Japan v.84 M. Takahashi;M. Yoshikura
  2. Phytochem v.19 J. Poplawski;J.T. Wrobel;T. Glinka
  3. Phytochem. v.19 Z. Dabrowski;J.T. Wrobel;K. Wojtasiewicz
  4. Phytochem. v.22 S.C. Shim;H.Y. Koh;B.H. Han
  5. Bull. Korean Chem. Soc. v.4 S.C. Shim;H.Y. Koh;B.H. Han
  6. J. Amer. Chem. Soc. v.104 N.C. Gonnella;K. Nakanishi;V.S. Martin;K.B. Sharpless
  7. J. Amer. Chem. Soc. v.102 N. Harada;Y. Tamai;Y. Takuyama;H. Uda
  8. J. Amer. Chem. Soc. v.100 N. Harada;H. Uda

피인용 문헌

  1. Biosynthesis of Panaxynol and Panaxydol in Panax ginseng vol.18, pp.7, 1986, https://doi.org/10.3390/molecules18077686