Applied Biological Chemistry

The Korean Society for Applied Biological Chemistry (한국응용생명화학회)
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Degradation of the Herbicide, Alachlor, by Soil Microorganisms -III. Degradation under an Upland Soil Condition-

제초제 Alachlor의 토양미생물에 의한 분해 -제 3 보. 밭토양 조건에서의 분해-

  • Lee, Jae-Koo (Department of Agricultural Chemistry, College of Agriculture Chung Buk National University)
  • 이재구 (충북대학교 농과대학 농화학과)
  • Published : 1986.06.30
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Abstract

Alachlor, 2-chloro-2',6'-diethyl-N-(methoxymethyl) acetanilide produced four major degradation products, when incubated under an upland soil condition for 80 days. They include 8-ethyl-2-hydroxy-N-(methoxymethyl)-1,2,3,4-tetrahydroquinoline (m/z 221), N-hydroxyacetyl-2,3-dihydro-7-ethylindole (m/z 205), 2-hydroxy-2',6'-diethyl-N-(methoxymethyl) acetanilide (m/z 251), and 9-ethyl-1,5-dihydrol-(methoxymethyl)-5-methyl-4,1-benzoxazepin-2 (3H)-one (m/z 249). The products turned out to be a little different from those obtained under the flooded paddy soil condition used in the previous paper. The plausible pathways for the degradation were proposed.

제초제 Alachlor가 밭토양 조건하에서 80일간 배양될 때 다음과 같은 4개의 주요분해 산물을 생성하였다. 즉 8-ethyl-2-hydroxy-N-(methoxymethyl)-1,2,3,4-tetrahydroguinoline (m/z 221). N-hydroxyacetyl-2,3-dihydro-7-ethylindole (m/z 205), 2-Hydroxy-2', 6',-diethyl-N-(methoxymethyl) acetanilide (m/z 251) 그리고. 9-ethyl-1,5-dihydro-1-(methoxymethyl)-5-methyl-4,1-beznoxazepin-2(3H)-one (m/z 249)이었다. 이들 분해산물은 제 1보에서 사용한 담수 논 토양조건하에서 얻었던 분해산물들과 약간 다르다는 것을 알게 되었다. 그리고 Alachlor의 가능한 분해 경로를 제시하였다.

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