대한화학회지 (Journal of the Korean Chemical Society)

  • 제29권5호
  • /
  • Pages.482-489
  • /
  • 1985
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

몰리브덴(V)의 퀴놀린계 착물합성과 그 성질 (제2보). 오클로로옥소몰리브덴(V) 산의 치환퀴놀린윰염

Synthesis and Characterization of Substituted Quinoline Complexes of Molybdenum (I). Substituted Quinolinium Salts of Pentachlorooxomolybdate (V)

  • 이광 (계명대학교 자연과학대학 화학과) ;
  • 오상오 (경북대학교 자연과학대학 화학과)
  • Kwang Lee (Department of Chemistry, Keimyung University) ;
  • Sang-Oh Oh (Department of Chemistry, Kyungpook National University)
  • 발행 : 1985.10.20
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초록

오클로로옥소몰리브덴(V)산의 치환퀴놀린윰염을 합성하고 착물의 원소분석, 적외선흡수 스펙트럼, 전자스펙트럼, 전기전도도를 측정하였다. 착물은 2:1전해질이고 치환퀴놀린류는 양이온 상태로 존재하고 있으며 착물의 음이온은 단위체이다. 착물의 결정장전이와 전하이동전이를 해석하였다.

The substituted quinolinium salts of pentachlorooxomolybdate (V) have been synthesized and characterized by means of the investigation of elemental analysis, infrared spectra, electron spectra, electric conductivity. The results of elemental analysis were well coincided with the theoretical value and all prepared salts were mononuclear complexes. The complexes were binary univalent electrolytes and analyzed d-d transition and charge transfer transition.

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