Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Reactions of Thianthrene Cation Radical Perchlorate with Azo-bis-2-phenoxy-2-propane and Azo-bis-2-(p-nitrophenoxy)-2-propane

  • Lee, Jae-Moon (Department of Chemistry, Seoul National University) ;
  • Kim, Kyong-Tae (Department of Chemistry, Seoul National University) ;
  • Shin, Jyng-Hyu (Department of Chemistry, Seoul National University)
  • Published : 1985.12.20
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Abstract

Thianthrene cation radical perchlorate (1) reacted with azo-bis-2-phenoxy-2-propane (6) to give thianthrene (2), cisthianthrene-5,10-dioxide, 5-(p-hydroxyphenyl) thianthrenium perchlorate (10), acetone, phenol, and 5-(2-propenyl) thianthrenium perchlorate (11) when the mole trtio of 1 to 6 was 1:1. Among the products, 11 was a new compound. However, when the corresponding mole ratio was 5:1, 11 was not formed. Similar result was obtained for azo-bis-2-(p-nitrophenoxy)-2-propane.

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References

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  1. An overview of some reactions of thianthrene cation radical. Products and mechanisms of their formation vol.27, pp.6, 1985, https://doi.org/10.1080/17415990600987965