Bulletin of the Korean Chemical Society

  • 제6권3호
  • /
  • Pages.138-140
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  • 1985
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Catalysis by the Fe(Ⅲ) Complex of N-Dodecyl-3,4-dihydroxybenzamide in the Hydroxylation of Anisole with Hydrogen peroxide$^*$

  • 발행 : 1985.06.20
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초록

Hydroxylation of anisole with $H_2O_2$ was investigated by employing Fe(III) ion and N-dodecyl-3,4-dihydroxybenzamide (DDHB) as a catalyst. The study was aimed at obtaining an insoluble catalyst with a long catalytic life, in view of the inactivation of the catechol portion of the catalyst during the reaction. The rate of decomposition of $H_2O_2$ under various conditions indicated that the reaction proceeds through the catalytic participation of $Fe(III){\cdot}DDHB$. Yield of the hydroxylation products under various conditions revealed that $Fe(III){\cdot}DDHB$ is not inactivated during the reaction.

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참고문헌

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